Reviews

研究業績（原著論文）

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研究業績（総説・その他）

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略歴

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受賞、学会活動等

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Accounts and Reviews

  1. Synthesis of Functionalized Episulfides, W. Ando and N. Tokitoh, Strain and Its Implications in Organic Chemistry, A. de Meijere and S. Blechert (eds.), Kluwer Academic Publishers, 59-75 (1989).
  2. New Progress in the Chemistry of Multiple-Bond Compounds of Heavier Typical Elements - in Pursuit of the Heavy Ketones, Tokitoh, N. J. Synth. Org. Chem. Jpn. 1994, 52, 136-148.
  3. New Aspects in the Chemistry of Low-coordinate Compounds of Group 14 Elements, N. Tokitoh, Y. Matsuhashi, K. Shibata, T. Matsumoto, H. Suzuki, M. Saito, K. Manmaru, and R. Okazaki, Main Group Metal Chemistry 1994, 17, 55-65.
  4. "Heavy Ketones": The Heavier Element Homologues of Ketones, N. Tokitoh and R. Okazaki, Main Group Chemistry News 1995, 3, 4-11.
  5. The Chemistry of "Heavy Carbenes" and "Heavy Ketones", N. Tokitoh, Chemistry and Chemical Industry 1996, 49, 216-218.
  6. The Chemistry of Silaaromatic Compounds, N. Tokitoh, Keiso Kagaku Kyokai Shi 1997, 8, 3-15.
  7. Stable thioaldehydes and selenoaldehydes: Synthesis, structure and reactivity, Tokitoh, N.; Okazaki, R. Polish Journal of Chemistry 1998, 72, 971-1000.
  8. Synthesis, structure, and reactivity of kinetically stabilized low-coordinated organolead compounds, Kano, N.; Tokitoh, N.; Okazaki, R. J. Synth. Org. Chem. Jpn. 1998, 56, 919-930.
  9. Recent Advances in the Chemistry of Silicon-Heteroatom Multiple Bonds, N. Tokitoh and R. Okazaki, In The Chemistry of Organosilicon Compounds Vol. 2, S. Patai and Z. Rappoport, Eds. (Wiley, New York), Chapt. 17, 1063-1103 (1998).
  10. Does the Lead-Lead Double Bond Exist as a Stable Compound? A New Aspect in the Chemistry of Heavy Elements, N. Tokitoh, Chemistry (Kagaku) 1999, 54, 70-71.
  11. The chemistry of germanium-containing heavy ketones, Tokitoh, N.; Matsumoto, T.; Okazaki, R. Bull. Chem. Soc. Jpn. 1999, 72, 1665-1684.
  12. New Aspects of Boron-containing Low-Coordinate Compounds, N. Tokitoh, M. Ito, and R. Okazaki, Main Group Chemistry News 2000, 7, 27-36.
  13. Heavy ketones, the heavier element congeners of a ketone, Okazaki, R.; Tokitoh, N. Acc. Chem. Res. 2000, 33, 625-630.
  14. Recent topics in the chemistry of heavier congeners of carbenes, Tokitoh, N.; Okazaki, R. Coord. Chem. Rev. 2000, 210, 251-277.
  15. New aspects in the chemistry of low-coordinated inter-element compounds of heavier Group 15 elements, Tokitoh, N. J. Organomet. Chem. 2000, 611, 217-227.
  16. Recent advances in the chemistry of group 14-group 16 double bond compounds, Tokitoh, N.; Okazaki, R. Adv. Organomet. Chem. Vol 47 2001, 47, 121-166.
  17. 含ケイ素芳香族化合物の化学の新展開、時任宣博、Organometallic News 2002, 6-10.
  18. Multiply Bonded Germanium, Tin and Lead Compounds, N. Tokitoh and R. Okazaki, In The Chemistry of Organic Germanium, Tin and Lead Compounds Vol. 2, Z. Rappoport, Eds. (John Wiley & Sons, New York), Chapt. 13, 843-901 (2002).
  19. New progress in the chemistry of stable metallaaromatic compounds of heavier group 14 elements, Tokitoh, N. Acc. Chem. Res. 2004, 37, 86-94.
  20. Synthesis of aromatic species containing a heavier group 14 element by taking advantage of kinetic stabilization, Tokitoh, N. Bull. Chem. Soc. Jpn. 2004, 77, 429-441.
  21. Sila- and germacyclopropabenzenes, Sasamori, T.; Tokitoh, N. Organometallics 2006, 25, 3522-3532.
  22. A bulky silylene generated under mild conditions: Its application to the synthesis of organosilicon compounds, Takeda, N.; Tokitoh, N. Synlett 2007, 2483-2491.
  23. Approach to the synthesis of novel doubly bonded systems between heavier group 15 elements, Sasamori, T.; Tokitoh, N. J. Synth. Org. Chem. Jpn. 2007, 65, 688-699.
  24. Doubly bonded systems between heavier Group 15 elements, Sasamori, T.; Tokitoh, N. Dalton Trans. 2008, 1395-1408.
  25. Stable Heavier Carbene Analogues, Mizuhata, Y.; Sasamori, T.; Tokitoh, N. Chem. Rev. 2009, 109, 3479-3511.
  26. 含高周期14族元素芳香族化合物の化学、水畑吉行・時任宣博、有機合成化学協会誌、2011, 69, 691-704.
  27. Reactivity of Organoaluminum Compounds with Unique Coordination Modes, Agou, T; Tokitoh, N.J. Synth. Org. Chem. Jpn. 2017, 75, 723-734.
  28. 有機元素化学の探求: 未踏の結合と構造を求めて、時任宣博、Organometallic News, 2023, 18-23.
  29. Small Molecule Activation Based on Novel Heavier Group 13/15 Interelement Compounds, λ3,λ3-Phosphanylalumanes, T. Yanagisawa, Y. Mizuhata, N. Tokitoh, Bull. Chem. Soc. Jpn., 2023, 96, doi.org/10.1246/bcsj.20230186.
  30. Recent Progress in the Chemistry of Heavy Aromatics, S. Fujimori, Y. Mizuhata, N. Tokitoh, Proc. Jpn. Acad., Ser. B, 2023, 99, in press (2023).

Books

  1. 有機化合物事典、安藤亘編著、時任宣博・他７名共同執筆、朝倉書店 (1987).
  2. New Chemistry of Fused 1,2,3-Selenadiazoles and 1,2,3-Thiadiazoles, W. Ando and N. Tokitoh, Heteroatom Chemistry, ed. by E. Block, VCH Publishers Inc., 1-25 (1990).
  3. Synthesis and Reactions of Novel Organochalcogen Compounds Containing Group 14 Metals (Si, Ge, and Sn), N. Tokitoh, Y. Matsuhashi, T. Matsumoto, H. Suzuki, M. Saito, K. Manmaru, and R. Okazaki, "Frontiers of Organo-germanium, -tin, and -lead Chemistry", ed by E. Lukevics and L. Ignatovich, Latvian Institute of Organic Synthesis, 71-85 (1993).
  4. 5,5-Diaryl-1,2,3,4,5-tetrathiagermolanes, DiarylgermanethionesﾐAr(Ar')GeS4, Ar(Ar')Ge=S, R. Okazaki, N. Tokitoh, and T. Matsumoto in Synthetic Methods of Organometallic and Inorganic Chemistry (Ed by W. A. Herrmann) Vol. 2 ( Vol. Eds; N. Auner and U. Klingebiel) Thieme, New York, 260-269 (1996).
  5. Thiiranes and Thiirenes: Monocyclic, W. Ando, N. Choi, and N. Tokitoh in Comprehensive Heterocyclic Chemistry II (Eds; A. R. Katritzky, C, W. Rees, and E. F. Scriven) Vol. 1A (Ed by A. Padwa), Pergamon, Oxford, 173-240 (1996).
  6. Three-membered Rings with One Selenium or Tellurium Atom, N. Tokitoh, W. Ando, and N. Choi in Comprehensive Heterocyclic Chemistry II (Eds; A. R. Katritzky, C, W. Rees, and E. F. Scriven) Vol. 1A (Ed by A. Padwa), Pergamon, Oxford, 259-276 (1996).
  7. Three-membered Rings with Two Heteroatoms including Selenium or Tellurium, N. Tokitoh, N. Choi, and W. Ando in Comprehensive Heterocyclic Chemistry II (Eds; A. R. Katritzky, C, W. Rees, and E. F. Scriven) Vol. 1A (Ed by A. Padwa), Pergamon, Oxford, 457-468 (1996).
  8. フォックス・ホワイトセル「有機化学」、稲本直樹監訳、時任宣博・他７名共訳、丸善（1999）.
  9. Thiirenes and Their Derivatives, Selenirenes, and Tellurirenes, N. Tokitoh and W. Ando, In Science of Syntheses, Houben-Weyl Methods of Molecular Transformations, (Eds. D. Belllus, S. V. Ley, R. Noyori, M. Regitz, E. Schaumann, I. Shinkai, E. J. Thomas, and B. M. Trost), Vol. 9. Fully Unsaturated Small-Ring Heterocycles and Monocyclic Five-Membered Hetarenes with one Heteroatom (Eds. M. Regitz and G. Maas), George Thieme Velag, Stuttgart, 43-65 (2001).
  10. Digermenes and Digermanes; Metalated Germanium Compounds; Germanium Oxides, Sulfides, Selenides; Iminogermanes; Germenes; Germylenes, N. Takeda, N. Tokitoh, R. Okazaki, In Science of Syntheses, Houben-Weyl Methods of Molecular Transformations, (Eds. D. Belllus, S. V. Ley, R. Noyori, M. Regitz, E. Schaumann, I. Shinkai, E. J. Thomas, and B. M. Trost), Vol. 5. Organometallics, Compounds of Group 14 (Ge, Sn, Pb), (Ed. M. G. Moloney), George Thieme Velag, Stuttgart, 27-54 (2003).
  11. Tin Oxides, Sulfides, Slenides, and Tellurides (Double Bonded); Iminostannanes; Stannenes; Stannylenes, N. Takeda, N. Tokitoh, R. Okazaki, In Science of Syntheses, Houben-Weyl Methods of Molecular Transformations, (Eds. D. Belllus, S. V. Ley, R. Noyori, M. Regitz, E. Schaumann, I. Shinkai, E. J. Thomas, and B. M. Trost), Vol. 5. Organometallics, Compounds of Group 14 (Ge, Sn, Pb), (Ed. M. G. Moloney), George Thieme Velag, Stuttgart, 299-314 (2003).
  12. Diplumbenes and Diplumbanes; Metalated Lead Compounds; Organoplumbyl Oxides, Sulfides, Selenides, and Tellurides (Double Bonded); Plumbylenes, N. Takeda, N. Tokitoh, R. Okazaki, In Science of Syntheses, Houben-Weyl Methods of Molecular Transformations, (Eds. D. Belllus, S. V. Ley, R. Noyori, M. Regitz, E. Schaumann, I. Shinkai, E. J. Thomas, and B. M. Trost), Vol. 5. Organometallics, Compounds of Group 14 (Ge, Sn, Pb), (Ed. M. G. Moloney), George Thieme Velag, Stuttgart, 637-651 (2003).
  13. Polysulfido Complexes of Main Gtoup and Transition Metals, N. Takeda, N. Tokitoh, R. Okazaki, In Topics in Current Chemistry 231, "Elemental Sulfur and Sulfur-Rich Compounds II", Springer-Verlag, Berlin, Heiderberg, 153-202 (2003).
  14. Silylenes (and Germylenes, Stannylenes, Plumbylenes), N. Tokitoh and W. Ando, In "Reactive Intermediates Chemistry", Ed by Robert A. Moss, Matthew S. Platz, and Maitland Jones Jr., John Wiley & Sons, Inc., Hoboken, New Jersey, 651-715 (2004).
  15. 21世紀の有機ケイ素化学ー機能性物質科学の宝庫ー、玉尾皓平監修、時任宣博他共同執筆、シーエムシー出版 (2004).
  16. Group 14 Multiple Bonding, T. Sasamori and N. Tokitoh, In "Encyclopedia of Inorganic Chemistry, 2nd Edition", Ed by R. Bruce King, John Wiley & Sons, Chichester , 1698-1740 (2005).
  17. 化学　元素が彩る暮らしと未来、 玉尾皓平、高野幹夫編著、時任宣博・他13名共同執筆、クバプロ (2006).
  18. The Compounds Between Si, Ge, and Sn and Chalcogens (S, Se, and Te) Having Both a Single and Double Bond (Heavy Ketones), N. Takeda, N. Tokitoh, and R. Okazaki, In "Handbook of Chalcogen Chemistry : New Perspectives in Sulfur, Selenium and Tellurium", Ed by F. A. Devillanova, RSC Publishing, 195-222 (2007).
  19. 有機ケイ素化学の応用展開ー機能性物質のためのニューシーズー、玉尾皓平監修、時任宣博他共同執筆、シーエムシー出版 (2010).
  20. Silaaromatics and Related Compounds, Y. Mizuhata and N. Tokitoh, In "Organosilicon Compounds: Theory and Experiment (Synthesis)", Ed by V. Y. Lee, Academic Press Ltd. Elsevier Science Ltd., 619-641 (2017).
  21. Germaaromatic Compounds, Y. Mizuhata and N. Tokitoh, In "Organogermanium Compounds: Theory, Experiment, and Applications", Ed by V. Y. Lee, John Wiley & Sons Inc., 477-506 (2023).

Patents

  1. エノン還元酵素、山本浩明、木本訓弘、林　素子、河合　靖、時任宣博、特開2003-033185. 
  2. 変性ポリマーの製造方法、田邊祐介・中川隆太郎・時任宣博・笹森貴裕・水畑吉行・吾郷友宏、特開2017-31370.