Publication List (2013~)

2022年

1. Boron complexes of π-extended nitroxide ligands exhibiting threestate redox processes and near-infrared-II (NIR-II) absorption properties
   Nakamura, M.; Hyakutake, R.; Morisako, S.; Sasamori, T.; Mizuhata, Y.; Tokitoh, N.; Nakashima, K.; Fukumoto, H.; Agou, T.
   
   Chem. Sci.
   ,
   2022
   ,
   , in press.
   
2. Characterization of Resonance Structures in Aromatic Rings of Benzene and Its Heavier-Element Analogues
   Sugahara, T.; Hashizume, D.; Tokitoh, N.; Matsui, H.; Kishi, R.; Nakano, M.; Sasamori, T.
   
   PCCP
   ,
   2022
   ,
   , in press.
   
3. Synthesis of a Kinetically Stabilized 2,2-Dihydrosilene
   Garcia, J. A.; Yasui, Y.; Yukimoto, M.; Mizuhata, Y.; Tokitoh, N.
   
   Chem. Lett.
   ,
   2022
   , 51
   , 898–901.
   DOI: 10.1246/cl.220275
4. Control over Ligand-Exchange Positions of Thiolate-Protected Gold Nanoclusters Using Steric Repulsion of Protecting Ligands
   Suzuki, W.; Takahata, R.; Chiga, Y.; Kikkawa, S.; Yamazoe, S.; Mizuhata, Y.; Tokitoh, N.; Teranishi, T.
   
   J. Am. Chem. Soc.
   ,
   2022
   ,
   144
   , 12310-12320.
   DOI: 10.1021/jacs.2c03670
5. Glucose as a Protein-Condensing Cellular Solute
   Noda, N.; Jung, Y.; Ado, G.; Mizuhata, Y.; Higuchi, M.; Ogawa, T.; Ishidate, F.; Sato, S.; Kurata, H.; Tokitoh, N.; Uesugi, M.
   
   ACS Chem. Biol.
   ,
   2022
   ,
   17
   , 567-575.
   DOI: 10.1021/acschembio.1c00849
6. Amidinate Bromogermylene Resulting from Carbodiimide Insertion into Ar–GeBr Bond
   Sasamori, T.; Sugahara, T.; Tokitoh, N.
   
   Mendeleev Commun.
   ,
   2022
   ,
   32
   , 63-65.
   DOI: 10.1016/j.mencom.2022.01.020
7. 2-Germaazulene: Synthesis and Properties of 2-Heteraazulene Containing a Germanium Atom as a Skeletal Element
   Oshiro, T.; Mizuhata, Y.; Tokitoh, N.
   
   Chem. Lett.
   ,
   2022
   ,
   51
   , 312-316.
   DOI: 10.1246/cl.210773
8. Convergent Synthesis of E ‐Disilene by the Reduction of Diastereomerically Separable 1,2‐Dichlorodisilanes
   Jun‐i, Y.; Mizuhata, Y.; Tokitoh, N.
   
   Eur. J. Inorg. Chem.
   ,
   2022
   ,
   2022
   , e202100962.
   DOI: 10.1002/ejic.202100962
9. Template Synthesis of Novel Norcorrole Complexes with a Phenyl‐substituted Phosphorus Center
   Jun‐i, Y.; Mizuhata, Y.; Tokitoh, N.
   
   Eur. J. Org. Chem.
   ,
   2022
   ,
   2022
   , e202101312.
   DOI: 10.1002/ejoc.202101312
10. Reaction of an Overcrowded 1,2-Diaryl-1,2-Dibromodisilene with 1-Vinylcyclohepta-1,3,5-Triene: Isolation of a 2-Vinylsilacyclopropane Derivative and Its Thermal Conversion to a Silacyclopent-3-Ene Derivative
    Oshiro, T.; Mizuhata, Y.; Tokitoh, N.
    
    Heterocycles
    ,
    2022
    ,
    104
    , 389.
    DOI: 10.3987/COM-21-14585

2021年

11. A unique 1,4-silyl group migration from carbon to carbon: Formation of benzylic silane in the reaction of sterically hindered benzylic telluride with alkyllithium
    Garcia, J. A.; Yukimoto, M.; Mizuhata, Y.; Tokitoh, N.
    
    J. Organomet. Chem.
    ,
    2021
    ,
    956
    , 122119.
    DOI: 10.1016/j.jorganchem.2021.122119
12. Fused-Nonacyclic Multi-Resonance Delayed Fluorescence Emitter Based on Ladder-Thiaborin Exhibiting Narrowband Sky-Blue Emission with Accelerated Reverse Intersystem Crossing
    Nagata, M.; Min, H.; Watanabe, E.; Fukumoto, H.; Mizuhata, Y.; Tokitoh, N.; Agou, T.; Yasuda, T.
    
    Angew. Chem. Int. Ed.
    ,
    2021
    ,
    60
    , 20280-20285.
    DOI: 10.1002/anie.202108283
13. A Novel Reactivity of Phosphanylalumane (>P–Al<): Reversible Addition of a Saturated Interelement Bond to Olefins
    Yanagisawa, T.; Mizuhata, Y.; Tokitoh, N.
    
    Chem. Eur. J.
    ,
    2021
    ,
    27
    , 11273-11278.
    DOI: 10.1002/chem.202101649
14. Alkali-Metal-Ion-Centered Sandwich Structures of 4-Bromophenyl[Tris(Pentafluorophenyl)]Borates and Their Synthetic Utility
    Iwai, K.; Mizuhata, Y.; Tokitoh, N.
    
    Organometallics
    ,
    2021
    ,
    40
    , 570-577.
    DOI: 10.1021/acs.organomet.0c00711
15. Easily Separable Cyclic Oligosilanes with p‐Methoxyphenyl Groups and Their Stereoselective Functionalization
    Omatsu, Y.; Mizuhata, Y.; Tokitoh, N.
    
    Eur. J. Inorg. Chem.
    ,
    2021
    ,
    2021
    , 1005-1012.
    DOI: 10.1002/ejic.202001076
16. Conformational Control in Dirhodium(II) Paddlewheel Catalysts Supported by Chalcogen-Bonding Interactions for Stereoselective Intramolecular C–H Insertion Reactions
    Murai, T.; Lu, W.; Kuribayashi, T.; Morisaki, K.; Ueda, Y.; Hamada, S.; Kobayashi, Y.; Sasamori, T.; Tokitoh, N.; Kawabata, T.; Furuta, T.
    
    ACS Catal.
    ,
    2021
    ,
    11
    , 568–578.
    DOI: 10.1021/acscatal.0c03689
17. Decisive Effects of C-N Axial Chirality of Intermediary Enolates on the Stereochemical Course of β-Lactam Formation from β-Branched α-Amino Acid Derivatives via Memory of Chirality
    Hyakutake, R.; Yoshimura, T.; Sasamori, T.; Tokitoh, N.; Kawabata, T.
    
    Heterocycles
    ,
    2021
    ,
    103
    , 995.
    DOI: 10.3987/COM-21-S(K)74
18. Discovery of Self‐Assembling Small Molecules as Vaccine Adjuvants
    Jin, S.; Vu, H. T.; Hioki, K.; Noda, N.; Yoshida, H.; Shimane, T.; Ishizuka, S.; Takashima, I.; Mizuhata, Y.; Pe, K. B.; Ogawa, T.; Nishimura, N.; Packwood, D.; Tokitoh, N.; Kurata, H.; Yamasaki, S.; Ishii, K. J.; Uesugi, M.
    
    Angew. Chem. Int. Ed.
    ,
    2021
    ,
    60
    , 961-969.
    DOI: 10.1002/anie.202011604
19. Synthesis of Carbazole-Fused Azaborinesvia a Pd-Catalyzed C-H Activation-Cyclization Reaction
    Nagata, M.; Oshiro, T.; Mizuhata, Y.; Tokitoh, N.; Hosoya, T.; Yamada, S.; Konno, T.; Fukumoto, H.; Kubota, T.; Agou, T.
    
    Bull. Chem. Soc. Jpn
    ,
    2021
    ,
    94
    , 21-23.
    DOI: 10.1246/bcsj.20200129

2020

20. 2,2-Bis[3,5-bis(dimethylamino)phenyl]-1,1,1,3,3,3-hexamethyltrisilane
    Mizuhata, Y.; Iwai, K.; Tokitoh, N.
    
    IUCrData
    ,
    2020
    ,
    5
    , x201299.
    DOI: 10.1107/S2414314620012997
21. Reaction of Germabenzenylpotassium with TBDMSCl: Unusual Trimerization of Germabenzene Skeletons
    Mizuhata, Y.; Fujimori, S.; Tokitoh, N.
    
    Phosphorus, Sulfur, and Silicon and the Related Elements
    ,
    2020
    ,
    195
    , 936-939.
    DOI: 10.1080/10426507.2020.1804187
22. Synthesis and Properties of Thiophene-Fused Thiopyrylium Salts
    Nagahora, N.; Kitahara, K.; Mizuhata, Y.; Tokitoh, N.; Shioji, K.; Okuma, K.
    
    J. Org. Chem.
    ,
    2020
    ,
    XXX
    , XXX.
    DOI: 10.1021/acs.joc.0c00364
23. Insertion Reaction of Chalcogens into an Al–P Bond
    Yanagisawa, T.; Mizuhata, Y.; Tokitoh, N.
    
    Heterocycles
    ,
    2020
    ,
    100
    , XXX.
    DOI: 10.3987/COM-20-14255
24. Additive‐Free Conversion of Internal Alkynes by Phosphanylalumanes: Production of Phosphorus/Aluminum Frustrated Lewis Pairs
    Yanagisawa, T.; Mizuhata, Y.; Tokitoh, N.
    
    ChemPlusChem
    ,
    2020
    ,
    85
    , 933-942.
    DOI: 10.1002/cplu.202000239
25. Development of P- and N-Chirogenic Ligands Based on Chiral Induction from a Phosphorus Donor to a Nitrogen Donor in Palladium Complexes
    Iwamoto, T.; Mizuhata, Y.; Tokitoh, N.; Nakamura, M.
    
    Organometallics
    ,
    2020
    ,
    39
    , 1672-1677.
    DOI: 10.1021/acs.organomet.0c00154
26. Facile Preparation of α,ω-Diynes Bearing a Perfluoroalkylene Linker –(CF2)n– (n = 4,6) and Their Application for Co- or Rh-Catalyzed [2+2+2]Cycloaddition Reactions Affording Aromatic Compounds with Perfluoroalkylene Units
    Agou, T.; Saruwatari, S.; Shirai, T.; Kumon, T.; Yamada, S.; Konno, T.; Mizuhata, Y.; Tokitoh, N.; Sei, Y.; Fukumoto, H.; Kubota, T.
    
    J. Fluor. Chem.
    ,
    2020
    ,
    234
    , 109512.
    DOI: 10.1016/j.jfluchem.2020.109512
27. Helicenes Fused with Hexafluorocyclopentene (HFCP): Synthesis, Structure, and Properties
    Agou, T.; Kohara, M.; Tamura, Y.; Yamada, K.; Shiitsuka, K.; Hosoya, T.; Mizuhata, Y.; Tokitoh, N.; Hayashi, Y.; Moronuki, Y.; Ishii, A.; Tanaka, Y.; Muranaka, A.; Uchiyama, M.; Yamada, S.; Konno, T.; Fukumoto, H.; Kubota, T.
    
    European J. Org. Chem.
    ,
    2020
    ,
    2020
    , 1871-1880.
    DOI: 10.1002/ejoc.202000152
28. A synthetic equivalent for unknown 1,3-zwitterions? – A K/OR phosphinidenoid complex with an additional Si–Cl function
    Kunzmann, R.; Omatsu, Y.; Schnakenburg, G.; Espinosa Ferao, A.; Yanagisawa, T.; Tokitoh, N.; Streubel, R.
    
    Chem. Commun.
    ,
    2020
    ,
    56
    , 3899-3902.
    DOI: 10.1039/D0CC00024H
29. Pentacyclic Ladder-Heteraborin Emitters Exhibiting High-Efficiency Blue Thermally Activated Delayed Fluorescence with an Ultrashort Emission Lifetime
    Agou, T.; Matsuo, K.; Kawano, R.; Park, I. S.; Hosoya, T.; Fukumoto, H.; Kubota, T.; Mizuhata, Y.; Tokitoh, N.; Yasuda, T.
    
    ACS Mater. Lett.
    ,
    2020
    ,
    2
    , 28-34.
    DOI: 10.1021/acsmaterialslett.9b00433

2019

30. Synthesis and Properties of Perfluoroalkylated TIPS-Pentacenes
    Agou, T.; Suzuki, S.; Kanno, Y.; Hosoya, T.; Fukumoto, H.; Mizuhata, Y.; Tokitoh, N.; Suda, Y.; Furukawa, S.; Saito, M.; Kubota, T.;
    
    Tetrahedron
    ,
    2019
    ,
    75
    , 130678.
    DOI: 10.1016/j.tet.2019.130678
31. Syntheses and Structures of Novel Λ3,Λ3-Phosphanylalumanes Fully Bearing Carbon Substituents and Their Substituent Effects
    Yanagisawa, T.; Mizuhata, Y.; Tokitoh, N.;
    
    Inorganics
    ,
    2019
    ,
    7
    , 132.
    DOI: 10.3390/inorganics7110132
32. Nature of the E⋯E′ interactions (E, E′ = O, S, Se, and Te) at naphthalene 1,8-positions with fine details of the structures: experimental and theoretical investigations
    Hayashi, S.; Uegaito, M.; Nishide, T.; Tanaka, E.; Nakanishi, W.; Sasamori, T.; Tokitoh, N.; Minoura, M.;
    
    New J. Chem.
    ,
    2019
    ,
    43
    , 14224-14237.
    DOI: 10.1039/C9NJ02198A
33. Near‐Infrared Circularly Polarized Luminescence through Intramolecular Excimer Formation of Oligo(p‐phenyleneethynylene)‐Based Double Helicates
    Miki, K.; Noda, T.; Gon, M.; Tanaka, K.; Chujo, Y.; Mizuhata, Y.; Tokitoh, N.; Ohe, K.;
    
    Chem. Eur. J.
    ,
    2019
    ,
    25
    , 9211-9216.
    DOI: 10.1002/chem.201901467
34. A Purified, Solvent‐Intercalated Precursor Complex for Wide‐Process‐Window Fabrication of Efficient Perovskite Solar Cells and Modules
    Ozaki, M; Shimazaki, A.; Jung, M.; Nakaike, Y.; Maruyama, N.; Yakumaru, S.; Rafieh, A. I.; Sasamori, T.; Tokitoh, N.; Ekanayake, P.; Murata, Y.; Murdey. R.; Wakamiya, A,;
    
    Angew. Chem. Int. Ed.
    ,
    2019
    ,
    58
    , 9389-9393.
    DOI: 10.1002/anie.201902235
35. The formation of a 1,4-disilabenzene and its isomerization into a disilabenzvalene derivative
    Sugahara, T.; Sasamori, T.; Tokitoh, N.;
    
    Dalton Trans.
    ,
    2019
    ,
    48
    , 9053-9056.
    DOI: 10.1039/C9DT01322A
36. A Mixed‐Anion System Consisting of a Germyl Anion and Anions Delocalized on Conjugated Carbon Ring Skeletons
    Fujimori, S.; Mizuhata, Y.; Tokitoh, N.;
    
    Chem. Eur. J.
    ,
    2019
    ,
    25
    , 6284-6289.
    DOI: 10.1002/chem.201900699
37. Reversible Isomerizations between 1,4-Digermabenzenes and 1,4-Digerma-Dewar-benzenes: Air-Stable Activators for Small Molecules
    Sugahara, T.; Guo, J.-D.; Hashizume, D.; Sasamori, T.; Tokitoh, N.;
    
    J. Am. Chem. Soc.
    ,
    2019
    ,
    141
    , 2263-2267.
    DOI: 10.1021/jacs.9b00129

2018

38. Dibromometallyl‐iron complexes generated by the recombination of an alumanyl‐iron complex with EBr3 (E = Al, Ga)
    Yanagisawa, T.; Mizuhata, Y.; Tokitoh, N.;
    
    Heteroatom Chem.
    ,
    2018
    , e21465.
    DOI: 10.1002/hc.21465
39. Stannabenzenylpotassium: The First Isolable Tin‐containing Benzene Derivative
    Fujimori, S.; Mizuhata, Y.; Tokitoh, N.;
    
    Chem. Eur. J.
    ,
    2018
    ,
    24
    , 17039-17045.
    DOI: 10.1002/chem.201804858
40. 2,5-Digermaselenophenes: Germanium Analogues of Selenophenes
    Sugahara, T.; Sasamori, T.; Tokitoh, N.;
    
    J. Am. Chem. Soc.
    ,
    2018
    ,
    140
    , 11206-11209.
    DOI: 10.1021/jacs.8b07588
41. The selective formation of a 1,2-disilabenzene from the reaction of a disilyne with phenylacetylene
    Sugahara, T.; Guo, J.-D.; Hashizume, D.; Sasamori, T.; Nagase, S.; Tokitoh, N.;
    
    Dalton Trans.
    ,
    2018
    ,
    47
    , 13318-13322.
    DOI: 10.1039/C8DT03081B
42. Synthesis of Dodecaallylhexasilacyclohexane and Its Convertibility
    Omatsu, Y.; Mizuhata, Y.; Tokitoh, N.;
    
    Z. Anorg. Allg. Chem.
    ,
    2018
    ,
    644
    , 930-934.
    DOI: 10.1002/zaac.201800171
43. Neutral, Cationic and Hydride‐substituted Siloxygermylenes
    Roy, M. M. D.; Fujimori, S.; Ferguson, M. J.; McDonald, R.; Tokitoh, N.; Rivard, E.;
    
    Chem. Eur. J.
    ,
    2018
    ,
    24
    , 14392-14399.
    DOI: 10.1002/chem.201802958
44. Syntheses and Structures of d10 Coinage Metal Complexes of Electron-Accepting Phosphine Ligands Featuring a 3,3,4,4,5,5-Hexafluorocyclopentene Framework
    Agou, T,; Wada, N.; Fujisawa, K.; Hosoya, T.; Mizuhata, Y.; Tokitoh, N.; Fukumoto, H.; Kubota, T.;
    
    Inorg. Chem.
    ,
    2018
    ,
    57
    , 9105-9114.
    DOI: 10.1021/acs.inorgchem.8b01111
45. Facile transformation of 2H,3H-decafluoropentane (HFC-4310mee) into (

    Z

    )-2H-nonafluoropent-2-ene and its application to the synthesis of polyfluorinated homoallylic ketones by Claisen rearrangement
    Agou, T.; Aso, D.; Kataoka, S.; Tuchimochi, R.; Fukumoto, H.; Yamazaki, T.; Kawasaki-Takasuka, T.; Mizuhata, Y.; Tokitoh, N.; Kubota, T.;
    
    J. Fluor. Chem.
    ,
    2018
    ,
    213
    , 74-79.
    DOI: 10.1016/j.jfluchem.2018.07.006
46. Generation of Stannabenzenes and Their Monomer-Dimer Equilibration
    Mizuhata, Y.; Fujimori, S.; Noda N.; Kanesato S,; Tokitoh, N.;
    
    Dalton. Trans.
    ,
    2018
    ,
    47
    , 14436-14444.
    DOI: 10.1039/C8DT02994F
47. Ru-Complexes of an Anionic Germabenzenyl Ligand
    Fujimori, S.; Mizuhata, Y.; Tokitoh, N.;
    
    Chem. Commun.
    ,
    2018
    ,
    54
    , 8044-8047.
    DOI: 10.1039/C8CC02845A
48. Synthesis and Structure of Lewis Base‐coordinated Phosphanylalumanes Bearing P‐H and Al‐Br Moieties
    Agou, T.; Ikeda, S.; Sasamori, T.; Tokitoh, N.;
    
    Eur. J. Inorg. Chem.
    ,
    2018
    , 1984-1987.
    DOI: 10.1002/ejic.201800175
49. Chalcogenation Reaction of Cyclic Digermenes
    Sugahara, T.; Sasamori, T.; Tokitoh, N.;
    
    Chem. Lett.
    ,
    2018
    ,
    47
    , 719-722.
    DOI: 10.1246/cl.180188
50. Heavy Phenyllithium and -sodium: Synthesis and Characterization of Germanium Analogues of Phenyl Anion (‘Germabenzenyl Anions’)
    Fujimori, S.; Mizuhata, Y.; Tokitoh, N.;
    
    Chem. Lett.
    ,
    2018
    ,
    47
    , 708-710.
    DOI: 10.1246/cl.180170
51. Intermolecular Chemo- and Regioselective Aromatic C-H Amination of Alkoxyarenes Promoted by Rhodium Nitrenoids
    Arai, K.; Ueda, Y.; Morisaki, K.; Furuta, T.; Sasamori, T.; Tokitoh, N.; Kawabata, T.;
    
    Chem. Commun.
    ,
    2018
    ,
    54
    , 2264-2267.
    DOI: 10.1039/C7CC09952E
52. Synthesis of a new highly-fluorinated cis-1,2-cyclopentanediol and its application for fluorinated oligoesters
    J. Fluor. Chem.
    ,
    2018
    ,
    210
    , 78-82.
    DOI: 10.1016/j.jfluchem.2018.03.002
53. Regioselective Cyclotrimerization of Terminal Alkynes Using a Digermyne
    Sugahara, T.; Guo, J.-D.; Sasamori, T,; Nagase, S.; Tokitoh, N.;
    
    Angew. Chem. Int. Ed.
    ,
    2018
    ,
    57
    , 3499-3503.
    DOI: 10.1002/anie.201801222
54. Reversible Addition of Terminal Alkenes to Digermynes
    Sugahara, T.; Guo, J.-D.; Sasamori, T,; Nagase, S.; Tokitoh, N.;
    
    Chem. Commun.
    ,
    2018
    ,
    54
    , 519-522.
    DOI: 10.1039/C7CC08555A
55. Synthesis and Characterization of N-Heterocyclic Carbene-Coordinated Silicon Compounds Bearing a Fused-Ring Bulky Eind Group
    Hayakawa, N.; Sadamori K.; Mizutani, S.; Agou, T.; Sugahara, T.; Sasamori, T.; Tokitoh, N.; Hashizume, D.; Matsuo, T.;
    
    Inorganics
    ,
    2018
    ,
    6
    , 30.
    DOI: 10.3390/inorganics6010030
56. 1,2-Dihalodigermenes bearing bulky Eind groups: synthesis, characterization, and conversion to halogermylenoids
    Hayakawa, N.; Sugahara, T.; Numata, Y.; Kawaai, H.; Yamatani, K.; Nishimura, N.; Goda, S.; Suzuki, Y.; Tanikawa, T.; Nakai, N.; Hashizume, D.; Sasamori, T.; Tokitoh, N.; Matsuo, T.;
    
    Dalton Trans.
    ,
    2018
    ,
    47
    , 814-822.
    DOI: 10.1039/C7DT03819D
57. A Redox‐Active Bis(ferrocenyl)germylene and Its Reactivity
    Suzuki, Y.; Sasamori, T.; Guo, J.-D.; Tokitoh, N.;
    
    Chem. Eur. J.
    ,
    2018
    ,
    24
    , 364-368.
    DOI: 10.1002/chem.201705598

2017

58. Synthesis of a Dichlorodigermasilane: Double Si–Cl Activation by a Ge=Ge Unit
    Sugahara, T.; Tokitoh, T.; Sasamori, T.;
    
    Inorganics
    ,
    2017
    ,
    5
    , 79.
    DOI: 10.3390/inorganics5040079
59. Development of Integrated Dry-Wet Synthesis Method for Metal Encapsulating Silicon Cage Superatoms of M@Si1

    6

    (M = Ti and Ta)
    Tsunoyama, H.; Akatsuka, H.; Shibuta, M.; Iwasa, T.; Mizuhata, Y.; Tokitoh, N.; Nakajima, A.;
    
    J. Phys. Chem. C
    ,
    2017
    ,
    121
    , 20507-20516.
    DOI: 10.1021/acs.jpcc.7b06449
60. Reactivity of Organoaluminum Compounds with Unique Coordination Modes
    Agou, T.; Tokitoh, N.,
    
    J. Synth. Org. Chem. Jpn.
    ,
    2017
    ,
    75
    , 723-734.
    DOI: 10.5059/yukigoseikyokaishi.75.723
61. Highly Bent 1,3-Digerma-2-silaallene
    Sugahara, T.; Sasamori, T.; Tokitoh, N.,
    
    Angew. Chem. Int. Ed.
    ,
    2017
    ,
    56
    , 9920-9923.
    DOI: 10.1002/anie.201706297
62. Synthesis and structures of zigzag shaped [12]cyclo-para-phenylene composed of dinaphthofuran units and biphenyl units
    Shouda, T.; Nakanishi, K.; Sasamori, T.; Tokitoh, N.; Kuramochi, K.; Tsubaki. K.,
    
    J. Org. Chem.
    ,
    2017
    ,
    82
    , 7850-7855.
    DOI: 10.1021/acs.joc.7b01053
63. Effects of counter anions,

    P

    -substituents, and solvents on optical and photophysical properties of 2-phenylbenzo[

    b

    ]phospholium salts
    Koyanagi, Y.; Kawaguchi, S.; Fujii, K.; Kimura, Y.; Sasamori, T.; Tokitoh, N.; Matano, Y.,
    
    Dalton Trans.
    ,
    2017
    ,
    46
    , 9517.
    DOI: 10.1039/C7DT01839H
64. Dodecaallylhexasilacyclohexane
    Mizuhata, Y.; Omatsu, Y.; Tokitoh, N.,
    
    IUCrData
    ,
    2017
    ,
    2
    , X170807.
    DOI: 10.1107/S2414314617008070
65. Designer Ligand Field for Blue-green Luminescence of Organoeuropium(II) Sandwich Complexes with Cyclononatetraenyl Ligands
    Kawasaki, K.; Sugiyama, R.; Tsuji, T.; Iwasa, T.; Tsunoyama, H.; Mizuhata, Y.; Tokitoh, N.; Nakajima, A.,
    
    Chem. Commun.
    ,
    2017
    ,
    53
    , 6557-6560.
    DOI: 10.1039/C7CC03045B
66. Skeletal Rearrangements of Polycyclic α-Ketols
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70. Germabenzenylpotassium: A Germanium Analogue of a Phenyl Anion
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71. Inorganic-Salt-Free Reduction in Main-Group Chemistry: Synthesis of a Dibismuthene and a Distibene
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74. Isolation and Ambident Reactivity of a Chlorogermylenoid
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75. Reactions of Li/Cl Phosphinidenoid Complexes with 1,3,4,5-Tetramethylimidazol-2-ylidene: A New Route to

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76. Selenium-Substitued Phosphaalkenes Obtained through 1,2-Elimination of Chlorosilane from Seleneylchlorophophines
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77. Synthesis and Structure of Lewis-Base-Free Phosphinoalumane Derivatives
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78. Acid-Responsive Absorption and Emission of 5-

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79. Reaction of a Stable Digermyne with Aceylenes: Synthesis of a 1,2-Digermabenzene and a 1,4-Digermabarrelene
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80. Synthesis and Structure of an Iron-Bromoalumanyl Complex with a Tri-Coordinated Aluminum Center
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81. Computational Picture of Silyl Transfer from Silylsilatranes to Arylpalladium Chloride
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82. Reactivities of a Barrelene-type Dialumane as an Equivalent of an Al=Al Doubly-bonded Species
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83. Synthesis and Properties of Stable Alumoles
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84. [K(18-crown-6)][FeCp*(CO)

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2015

85. Reaction of a Stable Dialkyldigermyne with Ethylene
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86. Encapsulating Inorganic Acetylene, HBNH, Using Flanking Coordinative Interactions
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87. Ring Expansion to 1-Bromo-1-alumacyclonona-2,4,6,8-tetraene by Insertion of Two Alkyne Molecules into the Al–C Bonds
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88. Syntheses and Structures of a Stable Gallole Free of Lewis Base Coordination and Its Dianion
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89. Oxidation of an Allene Compound Bearing 1,8-Dichloroacridene Moieties and Photolysis of the Halogenated Allene Compound for the Generation of Triplet Carbenes
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90. Unexpected Photochemical Reactions of 2-Aryl-2-ethynyltrisilane Derivative
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91. Synthesis, Photochemical Properties, and Cytotoxicities of 2

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92. Synthesis and Characterization of a 1,2-Digermabenzene
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93. Formation of a Diaminoalkyne Derivatives by Dialumane-mediated Homocoupling of

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94. Photochemical (

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95. Synthesis of 1,2-Dialkynyldisilanes Incorporated in 10-Membered-Ring System
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96. Sulfurization of 4,5,6-triphospha[3]radialene
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2014

97. Unique Synthetic Approach toward a Phosphaalkene: Synthesis of a Selenium-substituted Phosphaalkene with Bulky Substituents
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98. Synthesis and Characterization of Binary-Complex Models of Ureas and 1,3-Dicarbonyl Compounds: Deeper Insights into Reaction Mechanisms Using Snap-Shot Structural Analysis
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99. Planar Chiral Tetrasubstituted [2.2]Paracyclophane: Optical Resolution and Functionalization
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100. Synthesis and Structure of a 1-Phospha-2-boraacenaphthene Derivative and Its Chalcogenation Reactions
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101. Physical properties of mononuclear organoeuropium sandwich complexes ligated by cyclooctatetraene and bis(trimethylsilyl) cyclooctatetraene
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102. Liquid-Phase Synthesis of Multidecker Organoeuropium Sandwich Complexes and Their Physical Properties
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103. Synthesis and Properties of Butterfly-Shaped Expanded Naphthofuran Derivatives
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104. Synthesis of a Rhodium Carbonyl Phosphaalkenyl-Phosphido Complex: A Phosphorus Congener of Schiff Base Type

     N

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     Matsumoto, T.; Sasamori, T.; Miyake, H.; Tokitoh, N.,
     
     Organometallics
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105. Oxidative kinetic resolution of racemic alkyl aryl carbinols by an electronically tuned chiral nitroxyl radical
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106. Syntheses and Structures of Terminal Arylalumylene Complexes
     Nagata, K.; Agou, T.; Tokitoh, N.,
     
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107. A Convenient Route to Synthetic Analogues of the Oxidized Form of High-Potential Iron-Sulfur Proteins
     Tanifuji, K.; Yamada, N.; Tajima, T.; Sasamori, T.; Tokitoh, N.; Matsuo, T.; Tamao, K.; Ohki, Y.; Tatsumi, K.,
     
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108. Reproducible Fabrication of Efficient Peroyskite-based Solar Cells: X-ray Crystallographic Studies on the Formation of CH

     3

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109. Facile Synthesis of Dibenzopentalene Dianions and Their Application as New π-Extended Ligands
     Kuwabara, T.; Ishimura, K.; Sasamori, T.; Tokitoh, N.; Saito, M.,
     
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110. Synthesis, structure and reactivity of a 1-bromoalumole
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111. Reactions of Diaryldibromodisilenes with

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     -Heterocyclic Carbenes: Formation of Formal Bis-NHC Adducts of Silyliumylidene Cations
     Agou, T.; Hayakawa, N.; Sasamori, T.; Matsuo, T.; Hashizume, D.; Tokitoh, N.,
     
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2013

112. 1,2-Bis(ferrocenyl)-Substituted Distibene and Dibismuthene: Sb=Sb and Bi=Bi Units as π Spacers between Two Ferrocenyl Units
     Sakagami, M.; Sasamori, T.; Sakai, H.; Furukawa, Y.; Tokitoh, N,
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113. Biomimetic Synthesis of Zeylanone and Zeylanone Epoxide by Dimerization of 2-Methyl-1,4-naphthoquinone
     Maruo, S.; Nishio, K.; Sasamori, T.; Tokitoh, N.; Kuramochi, K.; Tsubaki, K,
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114. Investigation of the Carboxylate Position during the Acylation Reaction Catalyzed by Biaryl DMAP Derivatives with an Internal Carboxylate
     Nishino, R.; Furuta, T.; Kan, K.; Sato, M.; Yamanaka, M.; Sasamori, T.; Tokitoh, N.; Kawabata, T.,
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115. Small-Molecule-Induced Clustering of Heparan Sulfate Promotes Cell Adhesion
     Takemoto, N.; Suehara, T.; Frisco, H. L.; Sato, S.; Sezaki, T.; Kusamori, K.; Kawazoe, Y.; Park, S. M.; Yamazoe, S.; Mizuhata, Y.; Inoue, R.; Miller, G. J.; Hansen, S. U.; Jayson, G. C.; Gardiner, J. M.; Kanaya, T.; Tokitoh, N.; Ueda, K.; Takakura, Y.; Kioka, N.; Nishikawa, M.; Uesugi, M.,
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116. Synthesis of a Dialumene-Benzene Adduct and Its Reactivity as a Synthetic Equivalent of a Dialumene
     Agou, T.; Wasano, T.; Jin, P.; Nagase, S.; Tokitoh, N.,
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117. Syntheses and Structures of an "Alumole" and Its Dianion
     Agou, T.; Wasano, T.; Jin, P.; Nagase, S.; Tokitoh, N.,
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118. 1,2-Bis(ferrocenyl)dipnictenes: Bimetallic Systems with a Pn=Pn Heavy π-Spacer (Pn: P, Sb, and Bi)
     Sakagami, M.; Sasamori, T.; Sakai, H.; Furukawa, Y.; Tokitoh, N.,
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119. A New Family of Multiple-Bond Compounds between Heavier Group 14 Elements
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120. Step-wise sulfurization of stable 1,2-bis(ferrocenyl)diphosphene
     Sasamori, T.; Sakagami, M.; Tokitoh, N.,
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121. Dimerization Reactions of 2-Bromo-3,5,6-trimethyl-1,4-benzoquinone
     Azuma, S.; Ota, M.; Ishida, A.; Isozaki, K.; Takaya, H.; Nakamura, M.; Sasamori, T.; Tokitoh, N.; Kuramochi, K.; Tsubaki, K.,
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122. A Cyclochiral Conformational Motif Constructed Using a Robust Hydrogen-Bonding Network
     Mishiro, K.; Furuta, T.; Sasamori, T.; Hayashi, K.; Tokitoh, N.; Futaki, S.; Kawabata, T.,
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2012

123. Reactions of an Overcrowded Silylene with Pyridines: Formation of a Novel 2H-1,2-Azasilepine and Its Further Cycloaddition
     Mizuhata, Y.; Sato, T.; Tokitoh, N.,
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124. Evidence for LiBr-Assisted Generation of a Silylene from a 1,2-Diaryl-1,2-dibromodisilene
     Han, J. S.; Sasamori, T.; Mizuhata, Y.; Tokitoh, N.,
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125. Synthesis of an Arylbromosilylene-Platinum Complex by Using a 1,2-Dibromodisilene As a Silylene Source
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126. Catalytic Activities for Olefin Polymerization: Titanium(III), Titanium(IV), Zirconium(IV), and Hafnium(IV) beta-Diketiminato, 1-Aza-1,3-butadienyl-Imido, and 1-Aza-2-butenyl-Imido Complexes Bearing an Extremely Bulky Substituent, the Tbt Group (Tbt=2,4,6-[(Me

     3

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     2

     CH]

     3

     )C

     6

     H

     2
     Hamaki, H.; Takeda, N.; Nabika, M.; Tokitoh, N.,
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127. Generation of an Organotellurium(II) Cation
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128. Synthesis of Kinetically Stabilized 1,2-Dihydrodisilenes
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129. Synthesis and Properties of 4,5,6-Triphospha[3]radialene
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130. Exhaustive Syntheses of Naphthofluoresceins and Their Functions
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131. Asymmetric aldol reaction via memory of chirality
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132. Synthesis, Structure, and Properties of a Stable 1,2-Dibromodialumane(4) Bearing a Bulky Aryl Substituent
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133. Three Different Dimerizations of 2-Bromo-3-methyl-1,4-naphthoquinones
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134. 1,2-Bis(ferrocenyl)digermene: A d-π Electron System Containing a Ge=Ge Unit
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