2022年
Boron complexes of π-extended nitroxide ligands exhibiting threestate redox processes and near-infrared-II (NIR-II) absorption properties
Nakamura, M.; Hyakutake, R.; Morisako, S.; Sasamori, T.; Mizuhata, Y.; Tokitoh, N.; Nakashima, K.; Fukumoto, H.; Agou, T.
Chem. Sci.
, 2022
, , in press.
Characterization of Resonance Structures in Aromatic Rings of Benzene and Its Heavier-Element Analogues
Sugahara, T.; Hashizume, D.; Tokitoh, N.; Matsui, H.; Kishi, R.; Nakano, M.; Sasamori, T.
PCCP
, 2022
, , in press.
Synthesis of a Kinetically Stabilized 2,2-Dihydrosilene
Garcia, J. A.; Yasui, Y.; Yukimoto, M.; Mizuhata, Y.; Tokitoh, N.
Chem. Lett.
, 2022
, 51, 898–901.
DOI: 10.1246/cl.220275
Control over Ligand-Exchange Positions of Thiolate-Protected Gold Nanoclusters Using Steric Repulsion of Protecting Ligands
Suzuki, W.; Takahata, R.; Chiga, Y.; Kikkawa, S.; Yamazoe, S.; Mizuhata, Y.; Tokitoh, N.; Teranishi, T.
J. Am. Chem. Soc.
, 2022
, 144
, 12310-12320.
DOI: 10.1021/jacs.2c03670
Glucose as a Protein-Condensing Cellular Solute
Noda, N.; Jung, Y.; Ado, G.; Mizuhata, Y.; Higuchi, M.; Ogawa, T.; Ishidate, F.; Sato, S.; Kurata, H.; Tokitoh, N.; Uesugi, M.
ACS Chem. Biol.
, 2022
, 17
, 567-575.
DOI: 10.1021/acschembio.1c00849
Amidinate Bromogermylene Resulting from Carbodiimide Insertion into Ar–GeBr Bond
Sasamori, T.; Sugahara, T.; Tokitoh, N.
Mendeleev Commun.
, 2022
, 32
, 63-65.
DOI: 10.1016/j.mencom.2022.01.020
2-Germaazulene: Synthesis and Properties of 2-Heteraazulene Containing a Germanium Atom as a Skeletal Element
Oshiro, T.; Mizuhata, Y.; Tokitoh, N.
Chem. Lett.
, 2022
, 51
, 312-316.
DOI: 10.1246/cl.210773
Convergent Synthesis of E ‐Disilene by the Reduction of Diastereomerically Separable 1,2‐Dichlorodisilanes
Jun‐i, Y.; Mizuhata, Y.; Tokitoh, N.
Eur. J. Inorg. Chem.
, 2022
, 2022
, e202100962.
DOI: 10.1002/ejic.202100962
Template Synthesis of Novel Norcorrole Complexes with a Phenyl‐substituted Phosphorus Center
Jun‐i, Y.; Mizuhata, Y.; Tokitoh, N.
Eur. J. Org. Chem.
, 2022
, 2022
, e202101312.
DOI: 10.1002/ejoc.202101312
Reaction of an Overcrowded 1,2-Diaryl-1,2-Dibromodisilene with 1-Vinylcyclohepta-1,3,5-Triene: Isolation of a 2-Vinylsilacyclopropane Derivative and Its Thermal Conversion to a Silacyclopent-3-Ene Derivative
Oshiro, T.; Mizuhata, Y.; Tokitoh, N.
Heterocycles
, 2022
, 104
, 389.
DOI: 10.3987/COM-21-14585
2021年
A unique 1,4-silyl group migration from carbon to carbon: Formation of benzylic silane in the reaction of sterically hindered benzylic telluride with alkyllithium
Garcia, J. A.; Yukimoto, M.; Mizuhata, Y.; Tokitoh, N.
J. Organomet. Chem.
, 2021
, 956
, 122119.
DOI: 10.1016/j.jorganchem.2021.122119
Fused-Nonacyclic Multi-Resonance Delayed Fluorescence Emitter Based on Ladder-Thiaborin Exhibiting Narrowband Sky-Blue Emission with Accelerated Reverse Intersystem Crossing
Nagata, M.; Min, H.; Watanabe, E.; Fukumoto, H.; Mizuhata, Y.; Tokitoh, N.; Agou, T.; Yasuda, T.
Angew. Chem. Int. Ed.
, 2021
, 60
, 20280-20285.
DOI: 10.1002/anie.202108283
A Novel Reactivity of Phosphanylalumane (>P–Al<): Reversible Addition of a Saturated Interelement Bond to Olefins
Yanagisawa, T.; Mizuhata, Y.; Tokitoh, N.
Chem. Eur. J.
, 2021
, 27
, 11273-11278.
DOI: 10.1002/chem.202101649
Alkali-Metal-Ion-Centered Sandwich Structures of 4-Bromophenyl[Tris(Pentafluorophenyl)]Borates and Their Synthetic Utility
Iwai, K.; Mizuhata, Y.; Tokitoh, N.
Organometallics
, 2021
, 40
, 570-577.
DOI: 10.1021/acs.organomet.0c00711
Easily Separable Cyclic Oligosilanes with p‐Methoxyphenyl Groups and Their Stereoselective Functionalization
Omatsu, Y.; Mizuhata, Y.; Tokitoh, N.
Eur. J. Inorg. Chem.
, 2021
, 2021
, 1005-1012.
DOI: 10.1002/ejic.202001076
Conformational Control in Dirhodium(II) Paddlewheel Catalysts Supported by Chalcogen-Bonding Interactions for Stereoselective Intramolecular C–H Insertion Reactions
Murai, T.; Lu, W.; Kuribayashi, T.; Morisaki, K.; Ueda, Y.; Hamada, S.; Kobayashi, Y.; Sasamori, T.; Tokitoh, N.; Kawabata, T.; Furuta, T.
ACS Catal.
, 2021
, 11
, 568–578.
DOI: 10.1021/acscatal.0c03689
Decisive Effects of C-N Axial Chirality of Intermediary Enolates on the Stereochemical Course of β-Lactam Formation from β-Branched α-Amino Acid Derivatives via Memory of Chirality
Hyakutake, R.; Yoshimura, T.; Sasamori, T.; Tokitoh, N.; Kawabata, T.
Heterocycles
, 2021
, 103
, 995.
DOI: 10.3987/COM-21-S(K)74
Discovery of Self‐Assembling Small Molecules as Vaccine Adjuvants
Jin, S.; Vu, H. T.; Hioki, K.; Noda, N.; Yoshida, H.; Shimane, T.; Ishizuka, S.; Takashima, I.; Mizuhata, Y.; Pe, K. B.; Ogawa, T.; Nishimura, N.; Packwood, D.; Tokitoh, N.; Kurata, H.; Yamasaki, S.; Ishii, K. J.; Uesugi, M.
Angew. Chem. Int. Ed.
, 2021
, 60
, 961-969.
DOI: 10.1002/anie.202011604
Synthesis of Carbazole-Fused Azaborinesvia a Pd-Catalyzed C-H Activation-Cyclization Reaction
Nagata, M.; Oshiro, T.; Mizuhata, Y.; Tokitoh, N.; Hosoya, T.; Yamada, S.; Konno, T.; Fukumoto, H.; Kubota, T.; Agou, T.
Bull. Chem. Soc. Jpn
, 2021
, 94
, 21-23.
DOI: 10.1246/bcsj.20200129
2020年
2,2-Bis[3,5-bis(dimethylamino)phenyl]-1,1,1,3,3,3-hexamethyltrisilane
Mizuhata, Y.; Iwai, K.; Tokitoh, N.
IUCrData
, 2020
, 5
, x201299.
DOI: 10.1107/S2414314620012997
Reaction of Germabenzenylpotassium with TBDMSCl: Unusual Trimerization of Germabenzene Skeletons
Mizuhata, Y.; Fujimori, S.; Tokitoh, N.
Phosphorus, Sulfur, and Silicon and the Related Elements
, 2020
, 195
, 936-939.
DOI: 10.1080/10426507.2020.1804187
Synthesis and Properties of Thiophene-Fused Thiopyrylium Salts
Nagahora, N.; Kitahara, K.; Mizuhata, Y.; Tokitoh, N.; Shioji, K.; Okuma, K.
J. Org. Chem.
, 2020
, 85
, 7748-7756.
DOI: 10.1021/acs.joc.0c00364
Insertion Reaction of Chalcogens into an Al–P Bond
Yanagisawa, T.; Mizuhata, Y.; Tokitoh, N.
Heterocycles
, 2020
, 100
, 1084.
DOI: 10.3987/COM-20-14255
Additive‐Free Conversion of Internal Alkynes by Phosphanylalumanes: Production of Phosphorus/Aluminum Frustrated Lewis Pairs
Yanagisawa, T.; Mizuhata, Y.; Tokitoh, N.
ChemPlusChem
, 2020
, 85
, 933-942.
DOI: 10.1002/cplu.202000239
Development of P- and N-Chirogenic Ligands Based on Chiral Induction from a Phosphorus Donor to a Nitrogen Donor in Palladium Complexes
Iwamoto, T.; Mizuhata, Y.; Tokitoh, N.; Nakamura, M.
Organometallics
, 2020
, 39
, 1672-1677.
DOI: 10.1021/acs.organomet.0c00154
Facile Preparation of α,ω-Diynes Bearing a Perfluoroalkylene Linker –(CF2)n– (n = 4,6) and Their Application for Co- or Rh-Catalyzed [2+2+2]Cycloaddition Reactions Affording Aromatic Compounds with Perfluoroalkylene Units
Agou, T.; Saruwatari, S.; Shirai, T.; Kumon, T.; Yamada, S.; Konno, T.; Mizuhata, Y.; Tokitoh, N.; Sei, Y.; Fukumoto, H.; Kubota, T.
J. Fluor. Chem.
, 2020
, 234
, 109512.
DOI: 10.1016/j.jfluchem.2020.109512
Helicenes Fused with Hexafluorocyclopentene (HFCP): Synthesis, Structure, and Properties
Agou, T.; Kohara, M.; Tamura, Y.; Yamada, K.; Shiitsuka, K.; Hosoya, T.; Mizuhata, Y.; Tokitoh, N.; Hayashi, Y.; Moronuki, Y.; Ishii, A.; Tanaka, Y.; Muranaka, A.; Uchiyama, M.; Yamada, S.; Konno, T.; Fukumoto, H.; Kubota, T.
European J. Org. Chem.
, 2020
, 2020
, 1871-1880.
DOI: 10.1002/ejoc.202000152
A synthetic equivalent for unknown 1,3-zwitterions? – A K/OR phosphinidenoid complex with an additional Si–Cl function
Kunzmann, R.; Omatsu, Y.; Schnakenburg, G.; Espinosa Ferao, A.; Yanagisawa, T.; Tokitoh, N.; Streubel, R.
Chem. Commun.
, 2020
, 56
, 3899-3902.
DOI: 10.1039/D0CC00024H
Pentacyclic Ladder-Heteraborin Emitters Exhibiting High-Efficiency Blue Thermally Activated Delayed Fluorescence with an Ultrashort Emission Lifetime
Agou, T.; Matsuo, K.; Kawano, R.; Park, I. S.; Hosoya, T.; Fukumoto, H.; Kubota, T.; Mizuhata, Y.; Tokitoh, N.; Yasuda, T.
ACS Mater. Lett.
, 2020
, 2
, 28-34.
DOI: 10.1021/acsmaterialslett.9b00433
2019年
Synthesis and Properties of Perfluoroalkylated TIPS-Pentacenes
Agou, T.; Suzuki, S.; Kanno, Y.; Hosoya, T.; Fukumoto, H.; Mizuhata, Y.; Tokitoh, N.; Suda, Y.; Furukawa, S.; Saito, M.; Kubota, T.;
Tetrahedron
, 2019
, 75
, 130678.
DOI: 10.1016/j.tet.2019.130678
Syntheses and Structures of Novel Λ3,Λ3-Phosphanylalumanes Fully Bearing Carbon Substituents and Their Substituent Effects
Yanagisawa, T.; Mizuhata, Y.; Tokitoh, N.;
Inorganics
, 2019
, 7
, 132.
DOI: 10.3390/inorganics7110132
Nature of the E⋯E′ interactions (E, E′ = O, S, Se, and Te) at naphthalene 1,8-positions with fine details of the structures: experimental and theoretical investigations
Hayashi, S.; Uegaito, M.; Nishide, T.; Tanaka, E.; Nakanishi, W.; Sasamori, T.; Tokitoh, N.; Minoura, M.;
New J. Chem.
, 2019
, 43
, 14224-14237.
DOI: 10.1039/C9NJ02198A
Near‐Infrared Circularly Polarized Luminescence through Intramolecular Excimer Formation of Oligo(p‐phenyleneethynylene)‐Based Double Helicates
Miki, K.; Noda, T.; Gon, M.; Tanaka, K.; Chujo, Y.; Mizuhata, Y.; Tokitoh, N.; Ohe, K.;
Chem. Eur. J.
, 2019
, 25
, 9211-9216.
DOI: 10.1002/chem.201901467
A Purified, Solvent‐Intercalated Precursor Complex for Wide‐Process‐Window Fabrication of Efficient Perovskite Solar Cells and Modules
Ozaki, M; Shimazaki, A.; Jung, M.; Nakaike, Y.; Maruyama, N.; Yakumaru, S.; Rafieh, A. I.; Sasamori, T.; Tokitoh, N.; Ekanayake, P.; Murata, Y.; Murdey. R.; Wakamiya, A,;
Angew. Chem. Int. Ed.
, 2019
, 58
, 9389-9393.
DOI: 10.1002/anie.201902235
The formation of a 1,4-disilabenzene and its isomerization into a disilabenzvalene derivative
Sugahara, T.; Sasamori, T.; Tokitoh, N.;
Dalton Trans.
, 2019
, 48
, 9053-9056.
DOI: 10.1039/C9DT01322A
A Mixed‐Anion System Consisting of a Germyl Anion and Anions Delocalized on Conjugated Carbon Ring Skeletons
Fujimori, S.; Mizuhata, Y.; Tokitoh, N.;
Chem. Eur. J.
, 2019
, 25
, 6284-6289.
DOI: 10.1002/chem.201900699
Reversible Isomerizations between 1,4-Digermabenzenes and 1,4-Digerma-Dewar-benzenes: Air-Stable Activators for Small Molecules
Sugahara, T.; Guo, J.-D.; Hashizume, D.; Sasamori, T.; Tokitoh, N.;
J. Am. Chem. Soc.
, 2019
, 141
, 2263-2267.
DOI: 10.1021/jacs.9b00129
2018年
Dibromometallyl‐iron complexes generated by the recombination of an alumanyl‐iron complex with EBr3 (E = Al, Ga)
Yanagisawa, T.; Mizuhata, Y.; Tokitoh, N.;
Heteroatom Chem.
, 2018
, e21465.
DOI: 10.1002/hc.21465
Stannabenzenylpotassium: The First Isolable Tin‐containing Benzene Derivative
Fujimori, S.; Mizuhata, Y.; Tokitoh, N.;
Chem. Eur. J.
, 2018
, 24
, 17039-17045.
DOI: 10.1002/chem.201804858
2,5-Digermaselenophenes: Germanium Analogues of Selenophenes
Sugahara, T.; Sasamori, T.; Tokitoh, N.;
J. Am. Chem. Soc.
, 2018
, 140
, 11206-11209.
DOI: 10.1021/jacs.8b07588
The selective formation of a 1,2-disilabenzene from the reaction of a disilyne with phenylacetylene
Sugahara, T.; Guo, J.-D.; Hashizume, D.; Sasamori, T.; Nagase, S.; Tokitoh, N.;
Dalton Trans.
, 2018
, 47
, 13318-13322.
DOI: 10.1039/C8DT03081B
Synthesis of Dodecaallylhexasilacyclohexane and Its Convertibility
Omatsu, Y.; Mizuhata, Y.; Tokitoh, N.;
Z. Anorg. Allg. Chem.
, 2018
, 644
, 930–934.
DOI: 10.1002/zaac.201800171
Neutral, Cationic and Hydride‐substituted Siloxygermylenes
Roy, M. M. D.; Fujimori, S.; Ferguson, M. J.; McDonald, R.; Tokitoh, N.; Rivard, E.;
Chem. Eur. J.
, 2018
, 24
, 14392-14399.
DOI: 10.1002/chem.201802958
Syntheses and Structures of d10 Coinage Metal Complexes of Electron-Accepting Phosphine Ligands Featuring a 3,3,4,4,5,5-Hexafluorocyclopentene Framework
Agou, T,; Wada, N.; Fujisawa, K.; Hosoya, T.; Mizuhata, Y.; Tokitoh, N.; Fukumoto, H.; Kubota, T.;
Inorg. Chem.
, 2018
, 57
, 9105-9114.
DOI: 10.1021/acs.inorgchem.8b01111
Facile transformation of 2H,3H-decafluoropentane (HFC-4310mee) into (
Z
)-2H-nonafluoropent-2-ene and its application to the synthesis of polyfluorinated homoallylic ketones by Claisen rearrangement
Agou, T.; Aso, D.; Kataoka, S.; Tuchimochi, R.; Fukumoto, H.; Yamazaki, T.; Kawasaki-Takasuka, T.; Mizuhata, Y.; Tokitoh, N.; Kubota, T.;
J. Fluor. Chem.
, 2018
, 213
, 74-79.
DOI: 10.1016/j.jfluchem.2018.07.006
Generation of Stannabenzenes and Their Monomer-Dimer Equilibration
Mizuhata, Y.; Fujimori, S.; Noda N.; Kanesato S,; Tokitoh, N.;
Dalton. Trans.
, 2018
, 47
, 14436-14444.
DOI: 10.1039/C8DT02994F
Ru-Complexes of an Anionic Germabenzenyl Ligand
Fujimori, S.; Mizuhata, Y.; Tokitoh, N.;
Chem. Commun.
, 2018
, 54
, 8044-8047.
DOI: 10.1039/C8CC02845A
Synthesis and Structure of Lewis Base‐coordinated Phosphanylalumanes Bearing P‐H and Al‐Br Moieties
Agou, T.; Ikeda, S.; Sasamori, T.; Tokitoh, N.;
Eur. J. Inorg. Chem.
, 2018
, 1984-1987.
DOI: 10.1002/ejic.201800175
Chalcogenation Reaction of Cyclic Digermenes
Sugahara, T.; Sasamori, T.; Tokitoh, N.;
Chem. Lett.
, 2018
, 47
, 719-722.
DOI: 10.1246/cl.180188
Heavy Phenyllithium and -sodium: Synthesis and Characterization of Germanium Analogues of Phenyl Anion (‘Germabenzenyl Anions’)
Fujimori, S.; Mizuhata, Y.; Tokitoh, N.;
Chem. Lett.
, 2018
, 47
, 708-710.
DOI: 10.1246/cl.180170
Intermolecular Chemo- and Regioselective Aromatic C-H Amination of Alkoxyarenes Promoted by Rhodium Nitrenoids
Arai, K.; Ueda, Y.; Morisaki, K.; Furuta, T.; Sasamori, T.; Tokitoh, N.; Kawabata, T.;
Chem. Commun.
, 2018
, 54
, 2264-2267.
DOI: 10.1039/C7CC09952E
Synthesis of a new highly-fluorinated cis-1,2-cyclopentanediol and its application for fluorinated oligoesters
J. Fluor. Chem.
, 2018
, 210
, 78-82.
DOI: 10.1016/j.jfluchem.2018.03.002
Regioselective Cyclotrimerization of Terminal Alkynes Using a Digermyne
Sugahara, T.; Guo, J.-D.; Sasamori, T,; Nagase, S.; Tokitoh, N.;
Angew. Chem. Int. Ed.
, 2018
, 57
, 3499-3503.
DOI: 10.1002/anie.201801222
Reversible Addition of Terminal Alkenes to Digermynes
Sugahara, T.; Guo, J.-D.; Sasamori, T,; Nagase, S.; Tokitoh, N.;
Chem. Commun.
, 2018
, 54
, 519-522.
DOI: 10.1039/C7CC08555A
Synthesis and Characterization of N-Heterocyclic Carbene-Coordinated Silicon Compounds Bearing a Fused-Ring Bulky Eind Group
Hayakawa, N.; Sadamori K.; Mizutani, S.; Agou, T.; Sugahara, T.; Sasamori, T.; Tokitoh, N.; Hashizume, D.; Matsuo, T.;
Inorganics
, 2018
, 6
, 30.
DOI: 10.3390/inorganics6010030
1,2-Dihalodigermenes bearing bulky Eind groups: synthesis, characterization, and conversion to halogermylenoids
Hayakawa, N.; Sugahara, T.; Numata, Y.; Kawaai, H.; Yamatani, K.; Nishimura, N.; Goda, S.; Suzuki, Y.; Tanikawa, T.; Nakai, N.; Hashizume, D.; Sasamori, T.; Tokitoh, N.; Matsuo, T.;
Dalton Trans.
, 2018
, 47
, 814-822.
DOI: 10.1039/C7DT03819D
A Redox‐Active Bis(ferrocenyl)germylene and Its Reactivity
Suzuki, Y.; Sasamori, T.; Guo, J.-D.; Tokitoh, N.;
Chem. Eur. J.
, 2018
, 24
, 364-368.
DOI: 10.1002/chem.201705598
2017年
Synthesis of a Dichlorodigermasilane: Double Si–Cl Activation by a Ge=Ge Unit
Sugahara, T.; Tokitoh, T.; Sasamori, T.;
Inorganics
, 2017
, 5
, 79.
DOI: 10.3390/inorganics5040079
Development of Integrated Dry-Wet Synthesis Method for Metal Encapsulating Silicon Cage Superatoms of M@Si1
6
(M = Ti and Ta)
Tsunoyama, H.; Akatsuka, H.; Shibuta, M.; Iwasa, T.; Mizuhata, Y.; Tokitoh, N.; Nakajima, A.;
J. Phys. Chem. C
, 2017
, 121
, 20507-20516.
DOI: 10.1021/acs.jpcc.7b06449
Reactivity of Organoaluminum Compounds with Unique Coordination Modes
Agou, T.; Tokitoh, N.,
J. Synth. Org. Chem. Jpn.
, 2017
, 75
, 723-734.
DOI: 10.5059/yukigoseikyokaishi.75.723
Highly Bent 1,3-Digerma-2-silaallene
Sugahara, T.; Sasamori, T.; Tokitoh, N.,
Angew. Chem. Int. Ed.
, 2017
, 56
, 9920-9923.
DOI: 10.1002/anie.201706297
Synthesis and structures of zigzag shaped [12]cyclo-para-phenylene composed of dinaphthofuran units and biphenyl units
Shouda, T.; Nakanishi, K.; Sasamori, T.; Tokitoh, N.; Kuramochi, K.; Tsubaki. K.,
J. Org. Chem.
, 2017
, 82
, 7850-7855.
DOI: 10.1021/acs.joc.7b01053
Effects of counter anions,
P
-substituents, and solvents on optical and photophysical properties of 2-phenylbenzo[
b
]phospholium salts
Koyanagi, Y.; Kawaguchi, S.; Fujii, K.; Kimura, Y.; Sasamori, T.; Tokitoh, N.; Matano, Y.,
Dalton Trans.
, 2017
, 46
, 9517.
DOI: 10.1039/C7DT01839H
Dodecaallylhexasilacyclohexane
Mizuhata, Y.; Omatsu, Y.; Tokitoh, N.,
IUCrData
, 2017
, 2
, X170807.
DOI: 10.1107/S2414314617008070
Designer Ligand Field for Blue-green Luminescence of Organoeuropium(II) Sandwich Complexes with Cyclononatetraenyl Ligands
Kawasaki, K.; Sugiyama, R.; Tsuji, T.; Iwasa, T.; Tsunoyama, H.; Mizuhata, Y.; Tokitoh, N.; Nakajima, A.,
Chem. Commun.
, 2017
, 53
, 6557-6560.
DOI: 10.1039/C7CC03045B
Skeletal Rearrangements of Polycyclic α-Ketols
Kawamura, M.; Kamo, S.; Azuma, S.; Kubo, K.; Sasamori, T.; Tokitoh, N.; Kuramochi, K.; Tsubaki, K.,
Org. Lett.
, 2017
, 19
, 301-303.
DOI: 10.1021/acs.orglett.6b03541
Asymmetric Intramolecular C–H Insertion Promoted by Dirhodium(II) Carboxylate Catalyst Bearing Axially Chiral Amino Acid Derivatives
Lu, W.-j.; Pei, X.; Murai, T.; Sasamori, T.; Tokitoh, N.; Kawabata, T.; Furuta, T.,
Synlett.
, 2017
, 28
, 679-683.
DOI: 10.1055/s-0036-1588674
Experimental and Theoretical Examination of the Radical Cations Obtained from the Chemical and Electrochemical Oxidation of 5-Aminothiazoles
Yamaguchi, K.; Murai, T.; Kutsumizu, S.; Miwa, Y.; Ebihara, M.; Guo, J.-D.; Tokitoh, N.,
ChemistryOpen
, 2017
, 6
, 282-287.
DOI: 10.1002/open.201700016
Nature of
of the
X---E—E---X
type at naphthalene 1,8-positions and model, elucidated by X-ray crystallographic analysis and QC calculations with the QTAIM approach
Tsubomoto, Y.; Hayashi, S.; Nakanishi, W.; Sasamori, T.; Tokitoh, N.,
Acta Cryst.
2017
, B73
, 265–275.
DOI: 10.1107/S205252061700364X
Germabenzenylpotassium: A Germanium Analogue of a Phenyl Anion
Mizuhata, Y.; Fujimori, S.; Sasamori, T.; Tokitoh, N.,
Angew. Chem. Int. Ed.
, 2017
, 56
, 4588-4592.
DOI: 10.1002/anie.201700801
- *Selected as a VIP, Inside Cover
Inorganic-Salt-Free Reduction in Main-Group Chemistry: Synthesis of a Dibismuthene and a Distibene
Majhi, P. K.; Ikeda, H.; Sasamori, T.; Hayato, T.; Kazushi, M.; Tokitoh, N.,
Organometallics
, 2017
, 36
, 1224-1226.
DOI: 10.1021/acs.organomet.7b001471
Pyridinium 5-aminothiazoles: specific photophysical properties and vapochromism in
halogenated solvents
Yamagchi, K.; Murai, T.; Tsuchiya, Y.; Miwa, Y.; Kutsumizu, S.; Sasamori, T.; Tokitoh, N.,
RSC Adv.
, 2017
, 7
, 18132-18135.
DOI: 10.1039/c7ra01896g
2016年
Activation of Dihydrogen by Masked Doubly Bonded Aluminum Species
Nagata, K.; Murosaki, T.; Agou, T.; Sasamori, T.; Matsuo, T.; Tokitoh, N.,
Angew. Chem. Int. Ed.
, 2016
, 55
, 12877-12880.
DOI: 10.1002/anie.201606684
- *Selected as a VIP, Inside Cover
Isolation and Ambident Reactivity of a Chlorogermylenoid
Suzuki, Y.; Sasamori, T.; Guo, J.-D.; Nagase, S.; Tokitoh, N.,
Chem. Eur. J.
, 2016
, 22
, 13784-13788.
DOI: 10.1002/chem.201602601
- *Selected as a Frontispiece
Reactions of Li/Cl Phosphinidenoid Complexes with 1,3,4,5-Tetramethylimidazol-2-ylidene: A New Route to
N-
Heterocyclic Carbene Adducts of Terminal Phosphinidene Complexes and an Unprecedented Transformation of an Oxaphosphirane Complex
Klein, M.; Schnakenburg, G.; Ferao, A. E.; Tokitoh, N.; Streubel R.,
Eur. J. Inorg. Chem.
, 2016
, 685-690.
10.1002/ejic.201500959
Selenium-Substitued Phosphaalkenes Obtained through 1,2-Elimination of Chlorosilane from Seleneylchlorophophines
Sasamori, T.; Franco, JMV.; Guo, J.-D.; Sugamata, K.; Nagase, S.; Streubel, R.; Tokitoh, T.,
Eur. J. Inorg. Chem.
, 2016
, 678-684.
DOI: 10.1002/ejic.201500989
Synthesis and Structure of Lewis-Base-Free Phosphinoalumane Derivatives
Agou, T.; Ikeda, S.; Sasamori, T.; Tokitoh, N.,
Eur. J. Inorg. Chem.
, 2016
, 623-627.
DOI: 10.1002/ejic.201501141
Acid-Responsive Absorption and Emission of 5-
N
-Arylaminothiazoles: Emission of White Light from a Single Fluorescent Dye and a Lewis Acid
Yamagushi, K.; Murai, T.; Guo, J.-D.; Sasamori, T.; Tokitoh, N.,
ChemistryOpen
, 2016
, 5
, 434-438.
DOI: 10.1002/open.201600059/
Reaction of a Stable Digermyne with Aceylenes: Synthesis of a 1,2-Digermabenzene and a 1,4-Digermabarrelene
Sugahara, T.; Guo, J.-D.; Sasamori, T.; Karatsu, Y.; Furukawa, Y.; Fera, A. E.; Nagase, S.; Tokitoh, N.,
Bull. Chem. Soc. Jpn.
, 2016
, 89
, 1375-1384.
DOI: 10.1246/bcsj.20160269
Synthesis and Structure of an Iron-Bromoalumanyl Complex with a Tri-Coordinated Aluminum Center
Agou, T.; Yanagisawa, T.; Sasamori, T.; Tokitoh, N.,
Bull. Chem. Soc. Jpn.
, 2016
, 89
, 1184-1186.
DOI: 10.1246/bcsj.20160151
Computational Picture of Silyl Transfer from Silylsilatranes to Arylpalladium Chloride
Guo, J.-D.; Sasamori, T.; Yamamoro, T.; Matsubara, H.; Nagase, S.; Yorimitsu, H.,
Bull. Chem. Soc. Jpn.
, 2016
, 89
, 192-194.
DOI: 10.1246/bcsj.20150343
Reactivities of a Barrelene-type Dialumane as an Equivalent of an Al=Al Doubly-bonded Species
Agou, T.; Nagata, K.; Sasamori, T.; Tokitoh, N.;,
Phosphorus, Sulfer and Silicon and the Relat. Elem.
, 2016
, 191
, 588-590.
DOI: 10.1080/10426507.2015.1128912
Synthesis and Properties of Stable Alumoles
Tokitoh, N.; Agou, T.; Wasano, T.; Sasamori, T.,
Phosphorus, Sulfer and Silicon and the Relat. Elem.
, 2016
, 191
, 584-587.
DOI: 10.1080/10426507.2015.1128911
[K(18-crown-6)][FeCp*(CO)
2
]
Mizuhata, Y.; Yanagisawa, T.; Sasamori, T.; Tokitoh, N.,
IUCrData
, 2016
, 1
, x160881.
DOI: 10.1107/S2414314616008816
2015年
Reaction of a Stable Dialkyldigermyne with Ethylene
Sasamori, T.; Sugahara, T.; Agou, T.; Sugamata, K.; Guo, J.-D.; Nagase, S.; Tokitoh, N.,
Chem. Sci.
, 2015
, 6
, 5526-5530.
DOI: 10.1039/C5SC01266J/
Encapsulating Inorganic Acetylene, HBNH, Using Flanking Coordinative Interactions
Swarnalar, A. K.; Hering-Junghans, C.; Nagata, K.; Feruson, M. J.; McDonald, R.; Tokitoh, N.; Rivard, E.,
Angew. Chem. Int. Ed.
, 2015
, 54
, 10666-10669.
DOI: 10.1002/anie.201504867
Ring Expansion to 1-Bromo-1-alumacyclonona-2,4,6,8-tetraene by Insertion of Two Alkyne Molecules into the Al–C Bonds
Agou, T.; Wasano, T.; Sasamori, T.; Guo, J.-D.; Nagase, S.; Tokitoh, N.,
Angew. Chem. Int. Ed.
, 2015
, 54
, 9568-9571.
DOI: 10.1002/anie.201504468
Syntheses and Structures of a Stable Gallole Free of Lewis Base Coordination and Its Dianion
Agou, T.; Wasano, T.; Sasamori, T.; Tokitoh, N.,
J. Phys. Org. Chem.
, 2015
, 28
, 104-107.
DOI: 10.1002/poc.3344
Oxidation of an Allene Compound Bearing 1,8-Dichloroacridene Moieties and Photolysis of the Halogenated Allene Compound for the Generation of Triplet Carbenes
Fuku-en, S.; Frukawa, K.; Sasamori, T.; Tokitoh, N.; Abe, M.; Yamamoto, M.,
J. Phys. Org. Chem.
, 2015
, 28
, 79-87.
DOI: 10.1002/poc.3398
Unexpected Photochemical Reactions of 2-Aryl-2-ethynyltrisilane Derivative
Egawa, Y.; Mizuhata, Y.; Sasamori, T.; Tokitoh, N.; Abe, M.; Yamamoto, M.,
Main Gr. Met. Chem.
, 2015
, 38
, 51-55.
DOI: 10.1515/mgmc-2014-0042
Synthesis, Photochemical Properties, and Cytotoxicities of 2
H
-Naphtho[1,2-
b
]pyran and Its Photodimers
Ota, M.; Sasamori, T.; Tokitoh, N.; Onodera, T.; Mizushina, Y.; Kuramochi, K. Tsubaki, K.,
J. Org. Chem.
, 2015
, 80
, 5687-5695.
DOI: 10.1021/acs.joc.5b00645
Synthesis and Characterization of a 1,2-Digermabenzene
Sasamori, T.; Sugahara, T.; Agou, T.; Guo, J.-D.; Nagase, S.; Tokitoh, N.,
Organometallics
, 2015
, 34
, 2106-2109.
DOI: 10.1021/om501204u
Formation of a Diaminoalkyne Derivatives by Dialumane-mediated Homocoupling of
t
-Butyl Isocyanide
Nagata, K.; Agou, T.; Sasamori, T.; Tokitoh, N.,
Chem. Lett.
, 2015
, 44
, 1610-1612.
DOI: 10.1246/cl.150688
Photochemical (
E
)–(
Z
) Isomerization of the P=C Double Bond in Triphospha[3]radialene–[M(CO)
5
] (M = W, Cr) Complexes
Sasamori, T.; Hirano, K.; Miyake, H.; Tokitoh, N.,
Chem. Lett.
, 2015
, 44
, 1240-1242.
DOI: 10.1246/cl.150422
Synthesis of 1,2-Dialkynyldisilanes Incorporated in 10-Membered-Ring System
Tokitoh, N.; Mizuhata, Y.; Egawa, Y.; Sasamori, T.,
Heterocycles
2015
, 90
, 1111-1123.
DOI: 10.3987/COM-14-S(K)81
Sulfurization of 4,5,6-triphospha[3]radialene
Miyake, H.; Sasamori, T.; Tokitoh, N.,
Phosphorus, Sulfur and Silicon and the Relat. Elem.
, 2015
, 190
, 1247-1250.
DOI: 10.1080/10426507.2014.991828
2014年
Unique Synthetic Approach toward a Phosphaalkene: Synthesis of a Selenium-substituted Phosphaalkene with Bulky Substituents
Sugamata, K.; Sasamori, T.; Tokitoh, N.,
Chem. Lett.
, 2014
, 43
, 95-96.
DOI: 10.1246/cl.130862
Synthesis and Characterization of Binary-Complex Models of Ureas and 1,3-Dicarbonyl Compounds: Deeper Insights into Reaction Mechanisms Using Snap-Shot Structural Analysis
Azuma, T.; Kobayashi, Y.; Sakata, K.; Sasamori, T.; Tokitoh, N.; Takemoto, Y.,
J. Org. Chem.
, 2014
, 79
, 1805-1817.
DOI: 10.1021/jo4028775
Planar Chiral Tetrasubstituted [2.2]Paracyclophane: Optical Resolution and Functionalization
Morisaki, Y.; Gon, M.; Sasamori, T.; Tokitoh, N.; Chujo, Y.,
J. Am. Chem. Soc.
, 2014
, 36
, 3350-3353.
DOI: 10.1021/ja412197j
Synthesis and Structure of a 1-Phospha-2-boraacenaphthene Derivative and Its Chalcogenation Reactions
Tsurusaki, A.; Sasamori, T.; Tokitoh, N.,
Chem. Eur. J.
, 2014
, 20
, 3752-3758.
DOI: 10.1002/chem.201304644
Physical properties of mononuclear organoeuropium sandwich complexes ligated by cyclooctatetraene and bis(trimethylsilyl) cyclooctatetraene
Tsuji, T.; Fukazawa, S.; Sugiyama, R.; Kawasaki, K.; Iwasa, T.; Tsunoyama, H.; Tokitoh, N.; Nakajima, A.,
Chem. Phys. Lett.
, 2014
, 595
, 144-150.
DOI: 10.1016/j.cplett.2014.01.034
Liquid-Phase Synthesis of Multidecker Organoeuropium Sandwich Complexes and Their Physical Properties
Tsuji, T.; Hosoya, N.; Fukazawa, S.; Sugiyama, R.; Iwasa, T.; Tsunoyama, H.; Hamaki, H.; Tokitoh, N.; Nakajima, A.,
J. Phys. Chem. C
, 2014
, 118
, 5896-5907.
DOI: 10.1021/jp4108014
Synthesis and Properties of Butterfly-Shaped Expanded Naphthofuran Derivatives
Nakanishi, K.; Sasamori, T.; Kuramochi, K.; Tokitoh, N.; Kawabata, T.; Tsubaki, K.,
J. Org. Chem.
, 2014
, 79
, 2625-2631.
DOI: 10.1021/jo500085a
Synthesis of a Rhodium Carbonyl Phosphaalkenyl-Phosphido Complex: A Phosphorus Congener of Schiff Base Type
N
,
N'
-Chelating Monoanionic Ligands
Matsumoto, T.; Sasamori, T.; Miyake, H.; Tokitoh, N.,
Organometallics
, 2014
, 33
, 1341-1344.
DOI: 10.1021/om500065n
Oxidative kinetic resolution of racemic alkyl aryl carbinols by an electronically tuned chiral nitroxyl radical
Hamada, S.; Wada, Y.; Sasamori, T.; Tokitoh, N.; Furura, T.; Kawabata, T.,
Tetrahedron Lett.
, 2014
, 55
, 1943-1945.
DOI: 10.1016/j.tetlet.2014.02.005
Syntheses and Structures of Terminal Arylalumylene Complexes
Nagata, K.; Agou, T.; Tokitoh, N.,
Angew. Chem. Int. Ed.
, 2014
, 53
, 3881-3884.
DOI: 10.1002/anie.201310559
A Convenient Route to Synthetic Analogues of the Oxidized Form of High-Potential Iron-Sulfur Proteins
Tanifuji, K.; Yamada, N.; Tajima, T.; Sasamori, T.; Tokitoh, N.; Matsuo, T.; Tamao, K.; Ohki, Y.; Tatsumi, K.,
Inorg. Chem.
, 2014
, 53
, 4000-4009.
DOI: 10.1021/ic402890k
Reproducible Fabrication of Efficient Peroyskite-based Solar Cells: X-ray Crystallographic Studies on the Formation of CH
3
NH
3
PbI
3
Layers
Wakamiya, A.; Endo, M.; Sasamori, T.; Tokitoh, N.; Ogomi, Y.; Hayase, S.; Murata, Y.,
Chem. Lett.
2014
, 43
, 711-713.
DOI: 10.1246/cl.140074
Facile Synthesis of Dibenzopentalene Dianions and Their Application as New π-Extended Ligands
Kuwabara, T.; Ishimura, K.; Sasamori, T.; Tokitoh, N.; Saito, M.,
Chem. Eur. J.
2014
, 20
, 7571-7575.
DOI: 10.1002/chem.201402304
Synthesis, structure and reactivity of a 1-bromoalumole
Wasano, T.; Agou, T.; Sasamori, T.; Tokitoh, N.,
Chem. Commun.
, 2014
, 50
, 8148-8150.
DOI: 10.1039/C4CC03470H
Reactions of Diaryldibromodisilenes with
N
-Heterocyclic Carbenes: Formation of Formal Bis-NHC Adducts of Silyliumylidene Cations
Agou, T.; Hayakawa, N.; Sasamori, T.; Matsuo, T.; Hashizume, D.; Tokitoh, N.,
Chem. Eur. J.
, 2014
, 20
, 9246-9249.
DOI: 10.1002/chem.201403083
2013年
1,2-Bis(ferrocenyl)-Substituted Distibene and Dibismuthene: Sb=Sb and Bi=Bi Units as π Spacers between Two Ferrocenyl Units
Sakagami, M.; Sasamori, T.; Sakai, H.; Furukawa, Y.; Tokitoh, N,
Chem. Asian. J.
2013
, 8
, 690-693.
Biomimetic Synthesis of Zeylanone and Zeylanone Epoxide by Dimerization of 2-Methyl-1,4-naphthoquinone
Maruo, S.; Nishio, K.; Sasamori, T.; Tokitoh, N.; Kuramochi, K.; Tsubaki, K,
Org. Lett.
2013
, 15
, 1556-1559.
Investigation of the Carboxylate Position during the Acylation Reaction Catalyzed by Biaryl DMAP Derivatives with an Internal Carboxylate
Nishino, R.; Furuta, T.; Kan, K.; Sato, M.; Yamanaka, M.; Sasamori, T.; Tokitoh, N.; Kawabata, T.,
Angew. Chem. Int. Ed.
2013
, 52
, 6445-6449.
Small-Molecule-Induced Clustering of Heparan Sulfate Promotes Cell Adhesion
Takemoto, N.; Suehara, T.; Frisco, H. L.; Sato, S.; Sezaki, T.; Kusamori, K.; Kawazoe, Y.; Park, S. M.; Yamazoe, S.; Mizuhata, Y.; Inoue, R.; Miller, G. J.; Hansen, S. U.; Jayson, G. C.; Gardiner, J. M.; Kanaya, T.; Tokitoh, N.; Ueda, K.; Takakura, Y.; Kioka, N.; Nishikawa, M.; Uesugi, M.,
J. Am. Chem. Soc.
2013
, 135
, 11032-11039.
Synthesis of a Dialumene-Benzene Adduct and Its Reactivity as a Synthetic Equivalent of a Dialumene
Agou, T.; Wasano, T.; Jin, P.; Nagase, S.; Tokitoh, N.,
Angew. Chem. Int. Ed.
2013
, 52
, 10818-10821.
Syntheses and Structures of an "Alumole" and Its Dianion
Agou, T.; Wasano, T.; Jin, P.; Nagase, S.; Tokitoh, N.,
Angew. Chem. Int. Ed.
2013
, 52
, 10031-10034.
1,2-Bis(ferrocenyl)dipnictenes: Bimetallic Systems with a Pn=Pn Heavy π-Spacer (Pn: P, Sb, and Bi)
Sakagami, M.; Sasamori, T.; Sakai, H.; Furukawa, Y.; Tokitoh, N.,
Bull. Chem. Soc. Jpn.
2013
, 86
, 1132-1143.
A New Family of Multiple-Bond Compounds between Heavier Group 14 Elements
Sasamori, T.; Tokitoh, N.,
Bull. Chem. Soc. Jpn.
2013
, 86
, 1005-1021.
Step-wise sulfurization of stable 1,2-bis(ferrocenyl)diphosphene
Sasamori, T.; Sakagami, M.; Tokitoh, N.,
J. Sulf. Chem.
2013
, 34
, 677-683.
Dimerization Reactions of 2-Bromo-3,5,6-trimethyl-1,4-benzoquinone
Azuma, S.; Ota, M.; Ishida, A.; Isozaki, K.; Takaya, H.; Nakamura, M.; Sasamori, T.; Tokitoh, N.; Kuramochi, K.; Tsubaki, K.,
Chem. Lett.
2013
, 42
, 1531-1533.
A Cyclochiral Conformational Motif Constructed Using a Robust Hydrogen-Bonding Network
Mishiro, K.; Furuta, T.; Sasamori, T.; Hayashi, K.; Tokitoh, N.; Futaki, S.; Kawabata, T.,
J. Am. Chem. Soc.
2013
, 135
, 13644-13647.
2012年
Reactions of an Overcrowded Silylene with Pyridines: Formation of a Novel 2H-1,2-Azasilepine and Its Further Cycloaddition
Mizuhata, Y.; Sato, T.; Tokitoh, N.,
Heterocycles
2012
, 84
, 413-418.
Evidence for LiBr-Assisted Generation of a Silylene from a 1,2-Diaryl-1,2-dibromodisilene
Han, J. S.; Sasamori, T.; Mizuhata, Y.; Tokitoh, N.,
Chem. Asian J.
2012
, 7
, 298-300.
Synthesis of an Arylbromosilylene-Platinum Complex by Using a 1,2-Dibromodisilene As a Silylene Source
Agou, T.; Sasamori, T.; Tokitoh, N.,
Organometallics
2012
, 31
, 1150-1154.
Catalytic Activities for Olefin Polymerization: Titanium(III), Titanium(IV), Zirconium(IV), and Hafnium(IV) beta-Diketiminato, 1-Aza-1,3-butadienyl-Imido, and 1-Aza-2-butenyl-Imido Complexes Bearing an Extremely Bulky Substituent, the Tbt Group (Tbt=2,4,6-[(Me
3
Si)
2
CH]
3
)C
6
H
2
Hamaki, H.; Takeda, N.; Nabika, M.; Tokitoh, N.,
Macromolecules
2012
, 45
, 1758-1769.
Generation of an Organotellurium(II) Cation
Sugamata, K.; Sasamori, T.; Tokitoh, N.,
Eur. J. Inorg. Chem.
2012
, 775-778.
Synthesis of Kinetically Stabilized 1,2-Dihydrodisilenes
Agou, T.; Sugiyama, Y.; Sasamori, T.; Sakai, H.; Furukawa, Y.; Takagi, N.; Guo, J. D.; Nagase, S.; Hashizume, D.; Tokitoh, N.,
J. Am. Chem. Soc.
2012
, 134
, 4120-4123.
Synthesis and Properties of 4,5,6-Triphospha[3]radialene
Miyake, H.; Sasamori, T.; Tokitoh, N.,
Angew. Chem. Int. Ed.
2012
, 51
, 3458-3461.
Exhaustive Syntheses of Naphthofluoresceins and Their Functions
Azuma, E.; Nakamura, N.; Kuramochi, K.; Sasamori, T.; Tokitoh, N.; Sagami, I.; Tsubaki, K.,
J. Org. Chem.
2012
, 77
, 3492-3500.
Asymmetric aldol reaction via memory of chirality
Watanabe, H.; Yoshimura, T.; Kawakami, S.; Sasamori, T.; Tokitoh, N.; Kawabata, T.,
Chem. Commun.
2012
, 48
, 5346-5348.
Synthesis, Structure, and Properties of a Stable 1,2-Dibromodialumane(4) Bearing a Bulky Aryl Substituent
Agou, T.; Nagata, K.; Sakai, H.; Furukawa, Y.; Tokitoh, N.,
Organometallics
2012
, 31
, 3806-3809.
Three Different Dimerizations of 2-Bromo-3-methyl-1,4-naphthoquinones
Azuma, S.; Nishio, K.; Kubo, K.; Sasamori, T.; Tokitoh, N.; Kuramochi, K.; Tsubaki, K.,
J. Org. Chem.
2012
, 77
, 4812-4820.
1,2-Bis(ferrocenyl)digermene: A d-π Electron System Containing a Ge=Ge Unit
Sasamori, T.; Miyamoto, H.; Sakai, H.; Furukawa, Y.; Tokitoh, N.,
Organometallics
2012
, 31
, 3904-3910.
The 4,5,6-triphospha[3]radialene dianion: a phosphorus analogue of the deltate dianion. A NICS(0)(π zz) examination of their aromaticity
Miyake, H.; Sasamori, T.; Wu, J. I. C.; Schleyer, P. V. R.; Tokitoh, N.,
Chem. Commun.
2012
, 48
, 11440-11442.
Synthesis of a stable 1,2-bis(ferrocenyl)diphosphene
Sasamori, T.; Sakagami, M.; Niwa, M.; Sakai, H.; Furukawa, Y.; Tokitoh, N.,
Chem. Commun.
2012
, 48
, 8562-8564.
Protonation-Assisted Conjugate Addition of Axially Chiral Enolates: Asymmetric Synthesis of Multisubstituted beta-Lactams from alpha-Amino Acids
Yoshimura, T.; Takuwa, M.; Tomohara, K.; Uyama, M.; Hayashi, K.; Yang, P.; Hyakutake, R.; Sasamori, T.; Tokitoh, N.; Kawabata, T.,
Chem. Eur. J.
2012
, 18
, 15330-15336.
Synthesis of 1,4-Phosphasilacyclohexa-2,5-Dienes Bearing Hydrogen or Chlorine Atoms on the Silicon Atoms
Mizuhata, Y.; Morikawa, S.; Tokitoh, N.,
Heterocycles
2012
, 86
, 1621-1635.
Asymmetric Intramolecular Conjugate Addition of Alpha-Amino Acid Derivatives Via Racemization-Free Equilibrium of Intermediary Chiral Enolates
Monguchi, D.; Yoshimura, T.; Irie, K.; Hayashi, K.; Majumdar, S.; Sasamori, T.; Tokitoh, N.; Kawabata, T.,
Heterocycles
2012
, 86
, 1483-1494.