高周期典型元素不飽和化合物の化学：新規物性・機能の探求

時任研究室の発表論文についてはこちらをご覧ください。以下には、グルーメンバー間共同研究についてのみ示します。

• Synthesis and Reactions of a Stable 1,2-Diaryl-1,2-dibromodisilene: A Precursor for Substituted Disilenes and a 1,2-Diaryldisilyne,
  • T. Sasamori, K. Hironaka, Y. Sugiyama, N. Takagi, S. Nagase, Y. Hosoi, Y. Furukawa, and N. Tokitoh, J. Am. Chem. Soc., 130, 13856-13857 (2008).
• Synthesis and Properties of Stable 2-Metallanaphthalenes of Heavier Group 14 Elements,
  • Y. Mizuhata, T. Sasamori, N. Nagahora, Y. Watanabe, Y. Furukawa, and N. Tokitoh, Dalton Trans., 4409-4418 (2008).
• 1,2-Bisferrocenyldisilene: A Multi-step Redox System with an Si=Si Double Bond,
  • T. Sasamori, A. Yuasa, Y. Hosoi, Y. Furukawa, N. Tokitoh, Organometallics, 27, 3325-3327 (2008).
• The Chemistry of Stable Silabenzenes,
  • N. Tokitoh, K. Wakita, T. Matsumoto, T. Sasamori, R. Okazaki, N. Takagi, M. Kimura, and S. Nagase, J. Chin. Chem. Soc., 55, 487-507 (2008).
• Generation, Isolation, and Reactivity of a Kinetically Stabilized Diphosphene Anion Radical,
  • N. Nagahora, T. Sasamori, Y. Hosoi, Y. Furukawa, and N. Tokitoh, J. Organomet. Chem., 693, 625-632 (2008).
• Kinetically Stabilized 1,1′-Bis[(E)-diphosphenyl]ferrocenes; Syntheses, Structures, Properties, and Reactivities,
  • N. Nagahora, T. Sasamori, Y. Watanabe, Y. Furukawa, and N. Tokitoh, Bull. Chem. Soc. Jpn., 80, 1884-1900 (2007).
• Synthesis and Properties of a Kinetically Stabilized 9-Silaphenanthrene,
  • N. Tokitoh, A. Shinohara, T. Matsumoto, T. Sasamori, N. Takeda, and Y. Furukawa, Organometallics, 26, 4048-4053 (2007).
• Synthesis and Properties of 9-Anthryldiphosphene,
  • T. Sasamori, A. Tsurusaki, N. Nagahora, K. Matsuda, Y. Kanemitsu, Y. Watanabe, Y. Furukawa, and N. Tokitoh, Chem. Lett., 35, 1382-1383 (2006).
• One-electron Reduction of Kinetically Stabilized Dipnictenes: Synthesis of Dipnictene Anion Radicals,
  • T. Sasamori, E. Mieda, N. Nagahora, K. Sato, D. Shiomi, T. Takui, Y. Hosoi, Y. Furukawa, N. Takagi, S. Nagase, and N. Tokitoh, J. Am. Chem. Soc., 128, 12582-12588 (2006).
• Synthesis and Characterization of Two Isomers of 14π-electron Germaaromatics: Kinetically Stabilized 9-Germaanthracene and 9-Germaphenanthrene,
  • T. Sasamori, K. Inamura, W. Hoshino, N. Nakata, Y. Mizuhata, Y. Watanabe, Y. Furukawa, and N. Tokitoh, Organometallics, 25, 3533-3536 (2006).
• Photophysical and Photochemical Processes of 9,10-Dihydro-9-silaphenanthrene Derivatives: Photochemical Formation and Electronic Structure of 9-Silaphenanthrenes,
  • H. Hiratsuka, H. Horiuchi, Y. Furukawa, H. Watanabe, A. Ishihara, T. Okutsu, S. Tobita, T. Yoshinaga, A. Shinohara, N. Tokitoh, M. Oba, and K. Nishiyama, J. Phys. Chem. A, 110, 3868-3874 (2006).
• Synthesis and Properties of a New Kinetically Stabilized Digermyne: New Insights for a Germanium Analogue of an Alkyne,
  • Y. Sugiyama, T. Sasamori, Y. Hosoi, Y. Furukawa, N. Takagi, S. Nagase, and N. Tokitoh, J. Am. Chem. Soc., 128, 1023-1031 (2006).
• Systematic Studies on Redox Behavior of Homonuclear Double-bond Compounds of Heavier Group 15 Elements,
  • T. Sasamori, E. Mieda, N. Nagahora, N. Takeda, N. Takagi, S. Nagase, and N. Tokitoh, Chem. Lett., 34, 166-167 (2005).

• Exciton fine structure in a single carbon nanotube revealed through spectral diffusion, 
  • Matsuda K, Inoue T, Murakami Y, Maruyama S, and Kanemitsu Y, Physical Review B in press.
• Three-component cascade energy transfer using oligonaphthalene skeletons, 
  • Tsubaki K, Takaishi K, Sue D, Matsuda K, Kanemitsu Y, and Kawabata T, The Journal of Organic Chemistry, in press
• Exciton dephasing and multiexciton recombinations in a single carbon nanotube, 
  • Matsuda K, Inoue T, Murakami Y, Maruyama S, and Kanemitsu Y, Physical Review B 77, (2008) 033406-1-033406-4.
• Photoluminescence intermittency in single CdSe nanoparticles: Environment dependence, 
  • Ito Y, Matsuda K, and Kanemitsu Y, Journal of Luminescence, 128, (2008) 868-870.
• Near-infrared near-field photoluminescence imaging spectroscopy of exciton localized states in GaInNAs/GaAs quantum wells due to nonuniform distribution of nitrogen,
  • Kubota R, Nakashima K, Mizuno D, Saiki T, Sakai M, Matsuda K, and Ishizuka T,  Journal of Nanophotonics, 1, (2007) 011592-1-011592-6.
• Mechanism of photoluminescence enhancement in single semiconductor nanocrystals on metal surfaces,
  • Ito, Y.; Matsuda, K.; Kanemitsu, Y. Physical Review B2007, 75, 03309-1-03309-4.
• Two-exciton state in GaSb/GaAs type II quantum dots studied using near-field photoluminescence spectroscopy,
  • Matsuda, K.; Nair, S. V.; Ruda, H. E.; Sugimoto, Y.; Saiki, T.; Yamaguchi, K. Applied Physics Letters2007, 90, 013101-1-013101-3.
• Exciton localization of single-walled carbon nanotubes revealed by femtosecond excitation correlation spectroscopy,
  • Hirori, H.; Matsuda, K.; Miyauchi, Y.; Maruyama, S.; Kanemitsu, Y. Physical Review Letters2006, 97, 257401-1-257401-4.
• Diameter dependence of exciton-phonon interaction in individual single-walled carbon nanotubes studied by microphotoluminescence spectroscopy,
  • Inoue, T.; Matsuda, K.; Murakami, Y.; Maruyama, S.; Kanemitsu, Y. Physical Review B2006, 73, 233401-1-233401-4.
• Photoluminescence properties of single Mn-doped CdS nanocrystals studied by scanning near-field optical microscopy,
  • Ishizumi, A.; Matsuda, K.; Saiki, T.; White, C. W.; Kanemitsu, Y. Applied Physics Letters2005, 87, 133104-1-133104-3.
• Local density of states mapping of a field-induced quantum dot by near-field photoluminescence microscopy,
  • Matsuda, K.; Saiki, T.; Nomura, S.; Aoyagi, Y. Applied Physics Letters2005, 87, 043112-1-043112-3.
• Ultra-fast and sensitive photo-induced phase switching in (EDO-TTF)2PF6,
  • Chollet, M.; Guerin, L.; Uchida, N.; Fukaya, S.; Ishikawa, T.; Koshihara, S.-y.; Matsuda, K.; Yamochi, H.; Ota, A.; Saito, G. Journal of Luminescence2005, 112, 275-278.
• カーボンナノチューブにおける発光現象と電子状態,
  • 松田一成 マテリアルステージ 2007, 7(4), 29-32.
• 磁場環境下で動作する低温近接場光学顕微鏡の開発,
  • 酒井優; 杉本義明; 松田一成; 斎木敏治 真空2006, 49(11), 15-18.
• 単一分子分光によるカーボンナノチューブの光物性,
  • 松田一成 光技術コンタクト2006, 44(3), 17-22.
• 光物性の基礎と応用：近接場分光法",
  • 松田一成 オプトロニクス2005, 286(10), 165-170.
• 単一カーボンナノチューブの発光イメージング・分光,
  • 松田一成; 丸山茂夫 顕微鏡2005, 40(2), 91-95. 

• Isomeric Forms of Heavier Main Group Hydrides: Experimental and Theoretical Studies of the [Sn(Ar)H]2 (Ar = Terphenyl) System,
  • E. Rivard, R. C. Fischer, R. Wolf, Y. Peng, W. A. Merrill, N. D. Schley, Z. Xhu, L. Pu, J. C. Fettinger, S. J. Teat, I. Nowik, R. H. Herber, N. Takagi, S. Nagase, and P. P. Power, J. Am. Chem. Soc., 129, 16197-16208 (2007).
• Synthesis and Structure of Pentaorganostannate Having Five Carbon Substituents,
  • M. Saito, S. Imaizumi, T. Tajima, K. Ishimura, and S. Nagase, J. Am. Chem. Soc., 129, 10974-10975 (2007).
• Do Lead Analogues of Alkynes Take a Multiply Bonded Structure?
  • N. Takagi and S. Nagase, Organometallics, 26, 3627-3629 (2007).
• Tin Analogues of Alkynes. Multiply Bonded Structures vs Singly Bonded Structures,
  • Takagi N.; Nagase, S. Organometallics, 2007, 26, 469-471.
• Effects of Bulky Substituent Groups on the Si-Si Triple Bonding in RSi≡SiR and the Short Ga-Ga Distance in Na2[RGaGaR]. A Theoretical Study,
  • Takagi N.; Nagase, S. J. Organomet. Chem., 2007, 692, 217-224.
• Synthesis of Stannaindenyl Anions and a Dianion,
  • Saito, M.; Shimosawa, M.; Yoshioka, M.; Ishimura, K.; Nagase, S. Organometallics, 2006, 25, 2967-2971.
• Comment on "Disproving a Silicon Analog of an Alkyne with the Aid of Topological Analyses of the Electronic Structure and Ab Initio Molecular Dynamics Calculations",
  • Frenking, G.; Krapp, A.; Nagase, S.; Takagi, N.; Sekiguchi, A. ChemPhysChem, 2006, 7, 799-800.
• Ab Initio and DFT Study of the 29Si NMR Chemical Shifts in RSi≡SiR,
  • Karni, M.; Apeloig, Y.; Takagi, N.; Nagase, S. Organometallics, 2005, 24, 6319-6330.

• Noncontact Temperature Measurements of Organic Layers in an Organic Light-Emitting Diode Using Wavenumber–Temperature Relations of Raman Bands
  • Sugiyama, T.; Furukawa, Y. Jpn. J. Appl. Phys.2008, 47, 3537-3539.
• Temperature Measurements of Organic Light-Emitting Diodes by Stokes and Anti-Stokes Raman Scattering
  • Tsuji, H.; Oda, A.; Kido, J.; Sugiyama, T.; Furukawa Y. Jpn. J. Appl. Phys.2008, 47, 2171-2173.
• Temperature Measurements of the PEDOT-PSS Layer in a Polymer Light-Emitting Diode by Stokes and anti-Stokes Raman Scattering"
  • Sugiyama, T.; Tsuji, H.; Furukawa, Y. Chem. Phys. Lett.2008, 453(4−6), 238−241.
• Raman Spectra of Langmuir−Blodgett and Langmuir−Schaefer Films of Polydiacetylene Prepared from 10,12-Pentacosadiynoic Acid
  • Seto, K.; Hosoi, Y.; Furukawa, Y. Chem. Phys. Lett.2007, 444(4–6), 328−332.
• Relationship between Film Structure and Electric Performance of Organic Field-Effect Transistors Based on Perylene Tetracarboxylic Diimine Derivatives,
  • Hosoi, Y.; Furukawa, Y. Mol. Cryst. Liq. Cryst. 2007, 471(1), 189−194.
• Air-Stable n-Channel Organic Field-Effect Transistors Based on N,N'-Bis(4-trifluoromethylbenzyl)perylene-3,4,9,10-tetracarboxylic Diimide,
  • Hosoi, Y.; Tsunami, D.; Ishii, H.; Furukawa, Y. Chem. Phys. Lett.2007, 436, 139-143.
• High Performance N-Channel Organic Field-Effect Transistors Based on N,N'-Dioctyl-3,4,9,10-Perylene Tetracarboxylic Diimine,
  • Hosoi, Y.; Furukawa, Y. Mol. Cryst. Liq. Cryst.2007, 462, 37-43.
• Voltage-Induced Infrared Spectra from the Organic Field-Effect Transistor Based on the N,N'-bis(3-methylphenyl)-N,N'-diphenyl-1,1'-biphenyl-4,4'-diamine (TPD),
  • Tsuji, H.; Furukawa, Y. Mol. Cryst. Liq. Cryst.2006, 455, 353-359.
• DFT Oligomer Approach to Vibrational Spectra of Poly(p-phenylenevinylene),
  • Honda, K.; Furukawa, Y.; Nishide, H. Vib. Spectrosc.2006, 40, 149-154.
• Organic Field-Effect Transistor Based on Polydiacetylene Prepared from 10, 12-Pentacosadiynoic Acid,
  • Koyanagi, T.; Muratsubaki, M.; Hosoi, Y.; Shibata, T.; Tsutsui, K.; Wada, Y.; Furukawa, Y. Chem. Lett.2006, 35, 20-21.
• IR Study on Stacking Manner of Peptide Nanorings in Peptide Nanotubes,
  • Nagai, Y.; Nakanishi, T.; Okamoto, H.; Takeda, K.; Furukawa, Y.; Usui, K.; Mihara, H. Jpn. J. Appl. Phys.2005, 44, 7654-7661.
• Low Temperature Synthesis of Extremely Dense and Vertically Alighed Single-Walled Carbon Nanotubes,
  • Zhong, G.; Iwasaki, T.; Honda, K.; Furukawa, Y.; Ohdomari, I.; Kawarada, H. Jpn. J. Appl. Phys.2005, 44, 1558-1561.
• Very High Yield Growth of Vertically Aligned Single-Walled Carbon Nanotube by Point-Arc Microwave Plasma CVD,
  • Zhong, G.; Iwasaki, T.; Honda, K.; Furukawa, Y.; Ohdomari, I.; Kawarada, H. Chemical Vapor Deposition2005, 11, 127-130.
• Raman Spectral Changes of PEDOT-PSS in Polymer Light-Emitting Diodes upon Operation,
  • Sakamoto, S.; Okumura, M.; Zhao, Z.; Furukawa, Y. Chem. Phys. Lett.2005, 412, 395-398.
• Crystalline/Amorphous Raman Markers of Hole-Transport Material NPD in Organic Light-Emitting Diodes,
  • Sugiyama, T.; Furukawa, Y.; Fujimura, H. Chem. Phys. Lett.2005, 405, 330-333.
• Conformational Analysis of p-Terphenyl by Vibrational Spectroscopy and Density Functional Theory Calculations,
  • Honda, K.; Furukawa, Y. J. Mol. Struct.2005, 735/736, 11-19. 

• Coplanar Oligo(p-phenylenedisilenylene)s Based on the Octaethyl-substituted s-Hydrindacenyl Groups, 
  • Fukazawa, A.; Li, Y.-M.; Yamaguchi, S.; Tsuji, H.; Tamao, K. J. Am. Chem. Soc.2007, 129 (46), 14164–14165.
• Intramolecular Singlet Excited Energy Transfer in a Zinc Porphyrin-Free-base Porphyrin Dyad Linked with an Si–Si σ-Bond, 
  • Shibano, Y.; Sasaki, M.; Kawanishi, Y.; Araki, Y.; Tsuji, H.; Ito, O.; Tamao, K. Chem. Lett.2007, 36 (9), 1112–1113.
• ３．Oligosilane Bridge-Length Dependence of Electron and Energy Transfer of Zinc Porphyrin-Oligosilane-Fullerene Hybrid Molecules, 
  • Sasaki, M.; Shibano, Y.; Tsuji, H.; Araki, Y.; Tamao, K.; Ito, O. J. Phys. Chem. A 2007, 111 (16), 2973–2979.
• Conformation Effect of Oligosilane Linker on Photoinduced Electron Transfer of Tetrasilane-Linked Zinc Porphyrin–[60]Fullerene Dyads,
  • Shibano, Y.; Sasaki, M.; Tsuji, H.; Araki, Y.; Ito, O.; Tamao, K. J. Organomet. Chem. 2007, 692, 356-367.
• Synthesis, Structure, and Properties of 9-Phospha-10-silatriptycenes and their Derivatives,
  • Tsuji, H.; Inoue, T.; Kaneta, Y.; Sase, S.; Kawachi, A.; Tamao, K. Organometallics 2006, 25, 6142-6148.
• Double ortho-Lithiation of (Diethylamino)diphenylphosphine oxide and tert-Butyldiphenylphosphine Oxide,
  • Tsuji, H.; Komatsu, S.; Kanda, Y.; Umehara, T.; Saeki, T.; Tamao, K. Chem. Lett. 2006, 32, 758-759.
• Photoinduced Electron Transfer of Dialkynyldisilane-Linked Zinc Porphyrin-Fullerene Dyad,
  • Tsuji, H.; Shibano, Y.; Sasaki, M.; Toganoh, M.; Kataoka, T.; Araki, Y.; Tamao, K.; Ito, O. Bull. Chem. Soc. Jpn.2006, 79, 1338-1346.
• All-anti-Octasilane: Conformation Control of Silicon Chains Using the Robust Bicyclic Trisilane as the Building Block,
  • Fukazawa, A.; Tsuji, H.; Tamao, K. J. Am. Chem. Soc.2006, 128, 6800-6801.
• Functional Group Compatible Palladium-Catalyzed Cross-Coupling Reactions between Aryllithium and Aryl Halide Mediated by a Five-Membered Cyclic Silyl Ether,
  • Son, E. C.; Tsuji, H.; Saeki, T.; Tamao, K. Bull. Chem. Soc. Jpn.2006, 79, 492-494.
• trans-Dichlorobis(10-dodecyl-9-phospha-10-silatriptycene-κP)palladium(II)",
  • Tsuji, H.; Inoue, T.; Sase, S.; Tamao, K. Acta Cryst. E2006, 62, m535-m537.
• Skeletal rearrangement of a bicylic 1,3-diphenyltrisilane during acid-induced dephenylation reactions,
  • Fukazawa, A.; Tsuji, H.; Tamao, K. Silicon Chemistry2005, 3, 157-163.
• Conformation Dependence of Photophysical Properties of σ-π Conjugation as Demonstrated by cis- and trans-1,2-Diaryl-1,2-disilacyclohexane Cyclic Systems,
  • Tsuji, H.; Shibano, Y.; Takahashi, T.; Kumada, M.; Tamao, K. Bull. Chem. Soc. Jpn. 2005, 78, 1334-1344. 

• Stannenes, distannenes, and stannynes,
  • Y. Mizuhata and N. Tokitoh
  • Tin Chemistry: Fundamentals, Applications and Frontiers, ed. by M. Gielen, A. G. Davies, K. Pannell, and E. Tiekink, John Wiley & Sons, Chichester, pp. 177-200.
• The Compounds Between Si, Ge, and Sn and Chalcogens (S, Se, and Te) Having Both a Single and Double Bond (Heavy Ketones), 
  • N. Takeda, N. Tokitoh, and R. Okazaki
  • Handbook of Chalcogen Chemistry : New Perspectives in Sulfur, Selenium and Tellurium, Ed by F. A. Devillanova, RSC Publishing, 195-222 (2007).
• 化学　元素が彩る暮らしと未来
  • 玉尾皓平、高野幹夫編著、時任宣博・他13名共同執筆、クバプロ (2006).
• Group 14 Multiple Bonding,
  • T. Sasamori and N. Tokitoh
  • Encyclopedia of Inorganic Chemistry, 2nd Edition, Ed by R. Bruce King, John Wiley & Sons, Chichester, 1698-1740 (2005).

• GaSb/GaAs quantum nanostructures by molecular beam epitaxy, 
  • Yamaguchi K, Tsukamoto S, Matsuda K
  • Handbook of self-assembled semiconductor nanostructures novel devices in photonics and electronics, edited by M. Henini, Elsevier B. V. in press

• Vibrational Spectroscopy of Conducting Polymers: Fundamentals and Applications
  • Y. Furukawa
  • Vibrational Spectroscopy of Polymers: Principles and Practice, N.J. Everall, J.M. Chalmers and P.R. Griffiths eds., John, Wiley & Sons, Chichester, pp. 537−556 (2007).
• 赤外・ラマン分光の有機電子デバイスへの応用
  • 古川行夫
  • 先端材料開発における振動分光分析法の応用，西岡利勝，錦田晃一，尾崎幸洋編，第5章第1節，シーエムシー出版，東京，pp. 184−195 (2007).
• 赤外分光法を用いたキャリア（構造・密度）の測定方法と評価
  • 古川行夫
  • 第5版実験化学講座9 物質の構造Ⅰ 分光上，日本化学会編，丸善，東京，pp. 67–78およびpp. 411–416 (2005).
• 「フーリエ変換型分光器」および「赤外吸収スペクトル測定」
  • 古川行夫
  • 最新導電性高分子全集−高導電率化/経時変化/汎用有機溶媒への溶解性向上−，第5章第1節，技術情報協会，東京，pp. 149−159 (2007).
• 「高分子の構造」、「高分子の機能」
  • 古川行夫
  • 放送大学大学院教材　田隅三生，濱田嘉昭共編，物質環境科学Ⅰ−分子から機能性物質・生体まで−，放送大学教育振興会，東京，pp. 105-135 (2005)